Nickel(II) Phosphate VSB-5: A Magnetic Nanoporous Hydrogenation Catalyst with 24-Ring Tunnels

Nanoporosity, good thermal stability, antiferromagnetic ordering, and hydrogenation with basic catalytic character are four important properties of the large‐pore (24MR), zeolitic nickel(II) phosphate, VSB‐5 (Ni20[(OH)12(H2O)6][(HPO4)8(PO4)4]⋅12 H2O), which has been prepared under alkaline hydrother...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2001-08, Vol.40 (15), p.2831-2834
Main Authors: Guillou, Nathalie, Gao, Qiuming, Forster, Paul M., Chang, Jong-San, Noguès, Marc, Park, Sang-Eon, Férey, Gérard, Cheetham, Anthony K.
Format: Article
Language:English
Subjects:
heterogeneous catalysis
hydrogenation
microporous materials
nickel
P ligands
zeolites
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Summary:Nanoporosity, good thermal stability, antiferromagnetic ordering, and hydrogenation with basic catalytic character are four important properties of the large‐pore (24MR), zeolitic nickel(II) phosphate, VSB‐5 (Ni20[(OH)12(H2O)6][(HPO4)8(PO4)4]⋅12 H2O), which has been prepared under alkaline hydrothermal conditions. The structure of VSB‐5 is depicted: NiO6 octahedra: green; PO4 tetrahedra: red.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20010803)40:15<2831::AID-ANIE2831>3.0.CO;2-Z