Comparative study for degradation of industrial dyes by electrochemical advanced oxidation processes with BDD anode in a laboratory stirred tank reactor

Comparative degradation of the industrial dyes Blue BR, Violet SBL and Brown MF 50 mg L−1 has been studied by the electrochemical oxidation (EOx), electro-Fenton (EF), photoelectro-Fenton (PEF) process based on BDD electrode. Each dye was tested in 0.05 mM Na2SO4 with 0.5 mM Fe2+ at pH 3.0, and elec...

Full description

Saved in:
Bibliographic Details
Published in:Chemosphere (Oxford) 2018-08, Vol.205, p.682-689
Main Authors: Alcocer, Salvador, Picos, Alain, Uribe, Agustín R., Pérez, Tzayam, Peralta-Hernández, Juan M.
Format: Article
Language:English
Subjects:
Electrochemical process
Industrial dyes
Waste water treatment
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c377t-9dce02bf02bc9a36574c073d2790a55e75979694b75a219e1696774ac5f1591e3
cites cdi_FETCH-LOGICAL-c377t-9dce02bf02bc9a36574c073d2790a55e75979694b75a219e1696774ac5f1591e3
container_end_page 689
container_issue
container_start_page 682
container_title Chemosphere (Oxford)
container_volume 205
creator Alcocer, Salvador
Picos, Alain
Uribe, Agustín R.
Pérez, Tzayam
Peralta-Hernández, Juan M.
description Comparative degradation of the industrial dyes Blue BR, Violet SBL and Brown MF 50 mg L−1 has been studied by the electrochemical oxidation (EOx), electro-Fenton (EF), photoelectro-Fenton (PEF) process based on BDD electrode. Each dye was tested in 0.05 mM Na2SO4 with 0.5 mM Fe2+ at pH 3.0, and electrolyzed in a stirred tank reactor under galvanostatic conditions with 2.0, 5.0, 7.0, 11.0 and 18.0 mA cm−2. Dyes were oxidized via hydroxyl radicals (OH) formed at the BDD anode from water oxidation coupled with Fenton's reaction cathodically produced hydrogen peroxide (H2O2). Under Na2SO4 medium close to 100% the decolorization was achieved. Through the color abatement rate the dyes behavior was analyzed at the beginning of the oxidation process. Dissolved Organic Carbon (DOC) was tested to evaluate the degradation. From DOC removal, it was established an increasing relative oxidation power of the EOx 
doi_str_mv 10.1016/j.chemosphere.2018.04.155
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2035247383</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0045653518308105</els_id><sourcerecordid>2035247383</sourcerecordid><originalsourceid>FETCH-LOGICAL-c377t-9dce02bf02bc9a36574c073d2790a55e75979694b75a219e1696774ac5f1591e3</originalsourceid><addsrcrecordid>eNqNUU1v1DAQtVARXQp_Abm3XhJsJ47Xx3bLl1SJC5wtx56wXpJ4aycL-Sf8XGa124ojh9FIz-_NG88j5JqzkjPevN-VbgtDzPstJCgF4-uS1SWX8gVZ8bXSBRd6fUFWjNWyaGQlL8nrnHeMoVjqV-RSaCV0I8SK_NnEYW-TncIBaJ5mv9AuJurhR7Ie0TjS2NEw-jlPKdie-gUybRcKPbgpxeMiwSFu_cGODjyNv8NZuMdnyBn5v8K0pXf399SO0QOOo5b2to3oG9OCviEllE52_EkTWIfoG_Kys32Gt-d-Rb5__PBt87l4-Prpy-b2oXCVUlOhvQMm2g7LaVs1UtWOqcoLpZmVEpTUSje6bpW0gmvgjW6Uqq2THZeaQ3VFbk5zcdvHGfJkhpAd9L0dIc7ZCFZJUatqXSFVn6guxZwTdGafwmDTYjgzx2DMzvwTjDkGY1htMBjUvjvbzO0A_ln5lAQSNicC4GcPAZLJLsDxoiHhpY2P4T9s_gIwpqhg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2035247383</pqid></control><display><type>article</type><title>Comparative study for degradation of industrial dyes by electrochemical advanced oxidation processes with BDD anode in a laboratory stirred tank reactor</title><source>ScienceDirect Freedom Collection</source><creator>Alcocer, Salvador ; Picos, Alain ; Uribe, Agustín R. ; Pérez, Tzayam ; Peralta-Hernández, Juan M.</creator><creatorcontrib>Alcocer, Salvador ; Picos, Alain ; Uribe, Agustín R. ; Pérez, Tzayam ; Peralta-Hernández, Juan M.</creatorcontrib><description>Comparative degradation of the industrial dyes Blue BR, Violet SBL and Brown MF 50 mg L−1 has been studied by the electrochemical oxidation (EOx), electro-Fenton (EF), photoelectro-Fenton (PEF) process based on BDD electrode. Each dye was tested in 0.05 mM Na2SO4 with 0.5 mM Fe2+ at pH 3.0, and electrolyzed in a stirred tank reactor under galvanostatic conditions with 2.0, 5.0, 7.0, 11.0 and 18.0 mA cm−2. Dyes were oxidized via hydroxyl radicals (OH) formed at the BDD anode from water oxidation coupled with Fenton's reaction cathodically produced hydrogen peroxide (H2O2). Under Na2SO4 medium close to 100% the decolorization was achieved. Through the color abatement rate the dyes behavior was analyzed at the beginning of the oxidation process. Dissolved Organic Carbon (DOC) was tested to evaluate the degradation. From DOC removal, it was established an increasing relative oxidation power of the EOx &lt; EF &lt; PEF, according with their decolorization trend. This study highlights the potential of the electrochemical/BDD process for the degradation of industrial dyes found in wastewaters under appropriate experimental conditions. [Display omitted] •Degradation of industrial tannery dyes at pH 3 increases EOx &lt; EF &lt; PEF.•Under Na2SO4 medium close to 100% the decolorization was achieved.•Mineralization of a mixed dye solution &gt;100% by PEF/BDD.•Hydrogen peroxide production in BDD electrode.</description><identifier>ISSN: 0045-6535</identifier><identifier>EISSN: 1879-1298</identifier><identifier>DOI: 10.1016/j.chemosphere.2018.04.155</identifier><identifier>PMID: 29729622</identifier><language>eng</language><publisher>England: Elsevier Ltd</publisher><subject>Electrochemical process ; Industrial dyes ; Waste water treatment</subject><ispartof>Chemosphere (Oxford), 2018-08, Vol.205, p.682-689</ispartof><rights>2018 Elsevier Ltd</rights><rights>Copyright © 2018 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c377t-9dce02bf02bc9a36574c073d2790a55e75979694b75a219e1696774ac5f1591e3</citedby><cites>FETCH-LOGICAL-c377t-9dce02bf02bc9a36574c073d2790a55e75979694b75a219e1696774ac5f1591e3</cites><orcidid>0000-0003-4817-2859</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29729622$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Alcocer, Salvador</creatorcontrib><creatorcontrib>Picos, Alain</creatorcontrib><creatorcontrib>Uribe, Agustín R.</creatorcontrib><creatorcontrib>Pérez, Tzayam</creatorcontrib><creatorcontrib>Peralta-Hernández, Juan M.</creatorcontrib><title>Comparative study for degradation of industrial dyes by electrochemical advanced oxidation processes with BDD anode in a laboratory stirred tank reactor</title><title>Chemosphere (Oxford)</title><addtitle>Chemosphere</addtitle><description>Comparative degradation of the industrial dyes Blue BR, Violet SBL and Brown MF 50 mg L−1 has been studied by the electrochemical oxidation (EOx), electro-Fenton (EF), photoelectro-Fenton (PEF) process based on BDD electrode. Each dye was tested in 0.05 mM Na2SO4 with 0.5 mM Fe2+ at pH 3.0, and electrolyzed in a stirred tank reactor under galvanostatic conditions with 2.0, 5.0, 7.0, 11.0 and 18.0 mA cm−2. Dyes were oxidized via hydroxyl radicals (OH) formed at the BDD anode from water oxidation coupled with Fenton's reaction cathodically produced hydrogen peroxide (H2O2). Under Na2SO4 medium close to 100% the decolorization was achieved. Through the color abatement rate the dyes behavior was analyzed at the beginning of the oxidation process. Dissolved Organic Carbon (DOC) was tested to evaluate the degradation. From DOC removal, it was established an increasing relative oxidation power of the EOx &lt; EF &lt; PEF, according with their decolorization trend. This study highlights the potential of the electrochemical/BDD process for the degradation of industrial dyes found in wastewaters under appropriate experimental conditions. [Display omitted] •Degradation of industrial tannery dyes at pH 3 increases EOx &lt; EF &lt; PEF.•Under Na2SO4 medium close to 100% the decolorization was achieved.•Mineralization of a mixed dye solution &gt;100% by PEF/BDD.•Hydrogen peroxide production in BDD electrode.</description><subject>Electrochemical process</subject><subject>Industrial dyes</subject><subject>Waste water treatment</subject><issn>0045-6535</issn><issn>1879-1298</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqNUU1v1DAQtVARXQp_Abm3XhJsJ47Xx3bLl1SJC5wtx56wXpJ4aycL-Sf8XGa124ojh9FIz-_NG88j5JqzkjPevN-VbgtDzPstJCgF4-uS1SWX8gVZ8bXSBRd6fUFWjNWyaGQlL8nrnHeMoVjqV-RSaCV0I8SK_NnEYW-TncIBaJ5mv9AuJurhR7Ie0TjS2NEw-jlPKdie-gUybRcKPbgpxeMiwSFu_cGODjyNv8NZuMdnyBn5v8K0pXf399SO0QOOo5b2to3oG9OCviEllE52_EkTWIfoG_Kys32Gt-d-Rb5__PBt87l4-Prpy-b2oXCVUlOhvQMm2g7LaVs1UtWOqcoLpZmVEpTUSje6bpW0gmvgjW6Uqq2THZeaQ3VFbk5zcdvHGfJkhpAd9L0dIc7ZCFZJUatqXSFVn6guxZwTdGafwmDTYjgzx2DMzvwTjDkGY1htMBjUvjvbzO0A_ln5lAQSNicC4GcPAZLJLsDxoiHhpY2P4T9s_gIwpqhg</recordid><startdate>20180801</startdate><enddate>20180801</enddate><creator>Alcocer, Salvador</creator><creator>Picos, Alain</creator><creator>Uribe, Agustín R.</creator><creator>Pérez, Tzayam</creator><creator>Peralta-Hernández, Juan M.</creator><general>Elsevier Ltd</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-4817-2859</orcidid></search><sort><creationdate>20180801</creationdate><title>Comparative study for degradation of industrial dyes by electrochemical advanced oxidation processes with BDD anode in a laboratory stirred tank reactor</title><author>Alcocer, Salvador ; Picos, Alain ; Uribe, Agustín R. ; Pérez, Tzayam ; Peralta-Hernández, Juan M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-9dce02bf02bc9a36574c073d2790a55e75979694b75a219e1696774ac5f1591e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Electrochemical process</topic><topic>Industrial dyes</topic><topic>Waste water treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alcocer, Salvador</creatorcontrib><creatorcontrib>Picos, Alain</creatorcontrib><creatorcontrib>Uribe, Agustín R.</creatorcontrib><creatorcontrib>Pérez, Tzayam</creatorcontrib><creatorcontrib>Peralta-Hernández, Juan M.</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Chemosphere (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alcocer, Salvador</au><au>Picos, Alain</au><au>Uribe, Agustín R.</au><au>Pérez, Tzayam</au><au>Peralta-Hernández, Juan M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Comparative study for degradation of industrial dyes by electrochemical advanced oxidation processes with BDD anode in a laboratory stirred tank reactor</atitle><jtitle>Chemosphere (Oxford)</jtitle><addtitle>Chemosphere</addtitle><date>2018-08-01</date><risdate>2018</risdate><volume>205</volume><spage>682</spage><epage>689</epage><pages>682-689</pages><issn>0045-6535</issn><eissn>1879-1298</eissn><abstract>Comparative degradation of the industrial dyes Blue BR, Violet SBL and Brown MF 50 mg L−1 has been studied by the electrochemical oxidation (EOx), electro-Fenton (EF), photoelectro-Fenton (PEF) process based on BDD electrode. Each dye was tested in 0.05 mM Na2SO4 with 0.5 mM Fe2+ at pH 3.0, and electrolyzed in a stirred tank reactor under galvanostatic conditions with 2.0, 5.0, 7.0, 11.0 and 18.0 mA cm−2. Dyes were oxidized via hydroxyl radicals (OH) formed at the BDD anode from water oxidation coupled with Fenton's reaction cathodically produced hydrogen peroxide (H2O2). Under Na2SO4 medium close to 100% the decolorization was achieved. Through the color abatement rate the dyes behavior was analyzed at the beginning of the oxidation process. Dissolved Organic Carbon (DOC) was tested to evaluate the degradation. From DOC removal, it was established an increasing relative oxidation power of the EOx &lt; EF &lt; PEF, according with their decolorization trend. This study highlights the potential of the electrochemical/BDD process for the degradation of industrial dyes found in wastewaters under appropriate experimental conditions. [Display omitted] •Degradation of industrial tannery dyes at pH 3 increases EOx &lt; EF &lt; PEF.•Under Na2SO4 medium close to 100% the decolorization was achieved.•Mineralization of a mixed dye solution &gt;100% by PEF/BDD.•Hydrogen peroxide production in BDD electrode.</abstract><cop>England</cop><pub>Elsevier Ltd</pub><pmid>29729622</pmid><doi>10.1016/j.chemosphere.2018.04.155</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-4817-2859</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0045-6535
ispartof Chemosphere (Oxford), 2018-08, Vol.205, p.682-689
issn 0045-6535
1879-1298
language eng
recordid cdi_proquest_miscellaneous_2035247383
source ScienceDirect Freedom Collection
subjects Electrochemical process
Industrial dyes
Waste water treatment
title Comparative study for degradation of industrial dyes by electrochemical advanced oxidation processes with BDD anode in a laboratory stirred tank reactor
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-14T14%3A00%3A10IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Comparative%20study%20for%20degradation%20of%20industrial%20dyes%20by%20electrochemical%20advanced%20oxidation%20processes%20with%20BDD%20anode%20in%20a%20laboratory%20stirred%20tank%20reactor&rft.jtitle=Chemosphere%20(Oxford)&rft.au=Alcocer,%20Salvador&rft.date=2018-08-01&rft.volume=205&rft.spage=682&rft.epage=689&rft.pages=682-689&rft.issn=0045-6535&rft.eissn=1879-1298&rft_id=info:doi/10.1016/j.chemosphere.2018.04.155&rft_dat=%3Cproquest_cross%3E2035247383%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c377t-9dce02bf02bc9a36574c073d2790a55e75979694b75a219e1696774ac5f1591e3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2035247383&rft_id=info:pmid/29729622&rfr_iscdi=true