Adsorbent new materials and composites produced in a single step

• Published in: Sensors and actuators. B, Chemical Chemical, 2009-03, Vol.137 (1), p.185-194
• Main Authors: Lima, R.R., Carvalho, R.A.M., Carvalho, A.T., Simões, E.W., da Silva, M.L.P.
• Format: Article
• Language: English
• Subjects: Adsorbent new materials; Hexamethyldisilazane; Organic fluorinated compound; Plasma polymerization
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2008.10.062

The aim of this work is the production and preliminary characterization of adsorbent new materials useful for sensor development. A new plasma chamber was simulated and designed in order to obtain multiple layers and/or composites in a single step. Plasma deposited organic fluorocompound and hexamethyldisilazane (HMDS) thin films were produced and tested as adsorbent layers. Chemical characterization used ellipsometry, Raman, infrared and X-ray photoelectron spectroscopy. Hydrophobic and oleophobic character were determined by contact angle measurements. Adsorption characteristics were evaluated using quartz crystal microbalance. Not only HMDS but also the fluorocompound can polymerize but intermixing and a double layer are only obtained in very narrow conditions. The films are adsorbent and mildly hydrophobic. Films deposited on a microchromatographic column can be used on sample pretreatment to remove and/or preconcentrate volatile organic compounds. Therefore, with this approach it is possible to obtain films with different monomers on double layer or composites, with organic/inorganic materials or particles and use them on sample pretreatment for chemical analysis.