Bowl-in-bowl complex formation with mixed sized calixarenes: adaptivity towards guest binding

We demonstrated the organization of two differently sized calixarenes C-methylresorcin[4]arene (RsC1) and either calix[6]arene (Calix6) or calix[8]arene (Calix8), where the lower rim of RsC1 partially overlaps with the upper rim of Calix6 or Calix8. An adaptive nature of the heteromacrocyclic assemb...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (52), p.7131-7134
Main Authors: Dawn, Arnab, Eisenhart, Andrew, Mirzamani, Marzieh, Beck, Thomas L, Kumari, Harshita
Format: Article
Language:English
Subjects:
Binding
Calixarenes
Complex formation
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Summary:We demonstrated the organization of two differently sized calixarenes C-methylresorcin[4]arene (RsC1) and either calix[6]arene (Calix6) or calix[8]arene (Calix8), where the lower rim of RsC1 partially overlaps with the upper rim of Calix6 or Calix8. An adaptive nature of the heteromacrocyclic assembly towards the binding of a model guest has been observed.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc03415j