Flowerlike NiCo2S4 Hollow Sub-Microspheres with Mesoporous Nanoshells Support Pd Nanoparticles for Enhanced Hydrogen Evolution Reaction Electrocatalysis in Both Acidic and Alkaline Conditions

• Published in: ACS applied materials & interfaces 2018-07, Vol.10 (26), p.22248-22256
• Main Authors: Sheng, Guoqing, Chen, Jiahui, Li, Yunming, Ye, Huangqing, Hu, Zhixiong, Fu, Xian-Zhu, Sun, Rong, Huang, Weixin, Wong, Ching-Ping
• Format: Article
• Language: English
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.8b05427

Flowerlike NiCo2S4 hollow sub-microspheres are synthesized through Cu2O templates to support Pd nanoparticles as high-efficiency catalysts for the hydrogen evolution reaction (HER). The diameter and shell size of NiCo2S4 hollow sub-microspheres are about 400 and 16 nm, respectively. In addition, the surface of the shells is constructed by petallike nanosheets. About 3 nm Pd particles uniformly incorporate with the flowerlike NiCo2S4 hollow sub-microsphere to form the NiCo2S4/Pd heterostructure. The NiCo2S4/Pd catalysts exhibit significantly lower overpotential of only 87 and 83 mV at 10 mA/cm2 for the HER in both acidic and alkaline conditions, respectively, relative to NiCo2S4 (247, 226 mV) and Pd (175, 385 mV) catalysts. Besides, the NiCo2S4/Pd catalysts also exhibit excellent stability of HER in these two conditions. The superior HER performance of NiCo2S4/Pd might be resulted from the unique architecture of metal nanoparticles anchored on the bimetallic sulfide flowerlike hollow sub-microspheres, which could provide high surface area, lots of active sites, strong synergetic effect, and stable structure.