Copper‐Vapor‐Assisted Growth and Defect‐Healing of Graphene on Copper Surfaces

Although there is significant progress in the chemical vapor deposition (CVD) of graphene on Cu surfaces, the industrial application of graphene is not realized yet. One of the most critical obstacles that limit the commercialization of graphene is that CVD graphene contains too many vacancies or sp...

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Bibliographic Details
Published in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2018-07, Vol.14 (30), p.e1801181-n/a
Main Authors: Lee, Hyo Chan, Bong, Hyojin, Yoo, Min Seok, Jo, Mankyu, Cho, Kilwon
Format: Article
Language:English
Subjects:
Adatoms
Chemical vapor deposition
Commercialization
Copper
Cu vapor
CVD
Defects
defect‐healing
grain
Graphene
Healing
Industrial applications
Investigations
Melting points
Nanotechnology
Nanotubes
Organic chemistry
Sublimation
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Summary:Although there is significant progress in the chemical vapor deposition (CVD) of graphene on Cu surfaces, the industrial application of graphene is not realized yet. One of the most critical obstacles that limit the commercialization of graphene is that CVD graphene contains too many vacancies or sp3‐type defects. Therefore, further investigation of the growth mechanism is still required to control the defects of graphene. During the growth of graphene, sublimation of the Cu catalyst to produce Cu vapor occurs inevitably because the process temperature is close to the melting point of Cu. However, to date few studies have investigated the effects of Cu vapor on graphene growth. In this study, how the Cu vapor produced by sublimation affects the chemical vapor deposition of graphene on Cu surfaces is investigated. It is found that the presence of Cu vapor enlarges the graphene grains and enhances the efficiency of the defect‐healing of graphene by CH4. It is elucidated that these effects are due to the removal by Cu vapor of carbon adatoms from the Cu surface and oxygen‐functionalized carbons from graphene. Finally, these insights are used to develop a method for the synthesis of uniform and high‐quality graphene. The role of Cu vapor in growth of chemical vapor deposition graphene on Cu surface is described. Cu vapor directly affects the growth kinetics of graphene. It increases the grain size of graphene, and assists defect‐healing processes during the growth of graphene. The injection of additional Cu vapor during graphene growth enables the synthesis of high‐quality graphene.
ISSN:1613-6810
1613-6829
DOI:10.1002/smll.201801181