E-Selective synthesis of vinyl sulfones via silver-catalyzed sulfonylation of styrenes

An efficient and highly E-selective protocol for the synthesis of vinyl sulfones is described. This simple protocol demonstrates the first synthesis of vinyl sulfones via a silver-catalyzed C-S bond coupling reaction. In addition, the success of the reaction was found to be critically dependent on t...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2018, Vol.16 (32), p.5748-5751
Main Authors: Gui, Qingwen, Han, Kang, Liu, Zhuoliang, Su, Zhaohong, He, Xiaoli, Jiang, Hongmei, Tian, Bufan, Li, Yangyan
Format: Article
Language:English
Subjects:
Chemical synthesis
Silver
Styrenes
Sulfones
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Summary:An efficient and highly E-selective protocol for the synthesis of vinyl sulfones is described. This simple protocol demonstrates the first synthesis of vinyl sulfones via a silver-catalyzed C-S bond coupling reaction. In addition, the success of the reaction was found to be critically dependent on the use of TEMPO as the additive.
ISSN:1477-0520
1477-0539
DOI:10.1039/c8ob01502c