Variations and sources of nitrous acid (HONO) during a severe pollution episode in Beijing in winter 2016

• Published in: The Science of the total environment 2019-01, Vol.648, p.253-262
• Main Authors: Zhang, Wenqian, Tong, Shengrui, Ge, Maofa, An, Junling, Shi, Zongbo, Hou, Siqi, Xia, Kaihui, Qu, Yu, Zhang, Hongxing, Chu, Biwu, Sun, Yele, He, Hong
• Format: Article
• Language: English
• Subjects: Daytime HONO budget; Haze; Homogeneous reaction; Nitrous acid measurement; Vehicle emissions
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2018.08.133

HONO is an important precursor of OH radical and plays a key role in atmospheric chemistry, but its source and formation mechanism remain uncertain, especially during complex atmospheric pollution processes. In this study, HONO mixing ratios were measured by a custom-made instrument during a severe pollution event from 16 to 23 December 2016, at an urban area of Beijing. The measurement was divided into three periods: I (haze), II (severe haze) and III (clean), according to the levels of PM2.5. This pollution episode was characterized by high levels of NO (75 ± 39 and 94 ± 40 ppbV during periods I and II, respectively) and HONO (up to 10.7 ppbV). During the nighttime, the average heterogeneous conversion frequency during the two haze periods were estimated to be 0.0058 and 0.0146 h−1, and it was not the important way to form HONO. Vehicle emissions contributed 52% (±16)% and 40% (±18)% to ambient HONO at nighttime during periods I and II. The contribution of homogeneous reaction of NO with OH should be reconsidered under high-NOx conditions and could be noticeable to HONO sources during this pollution event. Furthermore, HONO was positively correlated with PM2.5 during periods I and II, suggesting a potential chemical link between HONO and haze particles. [Display omitted] •High HONO concentrations were observed in a severe pollution episode in Beijing.•The NO2 conversion was not an important pathway to form HONO at nighttime.•Direct emissions could be critical to the observed HONO.•The homogeneous reaction could be a noticeable HONO source.•Good relation of HONO with PM2.5 implied a chemical link between HONO and PM2.5.