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Rhodium(III)‐Catalyzed Oxidative Annulation of Acrylic Acid with Alkynes: An Easy Approach to the Synthesis of α‐Pyrones

A highly efficient rhodium(III)‐catalyzed direct oxidative annulation of acrylic acid with alkynes to form α‐pyrones was developed. Various substituted acrylic acids were compatible in this transformation, affording the corresponding products in moderate to excellent yields under mild conditions. Py...

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Bibliographic Details
Published in:Chemistry, an Asian journal an Asian journal, 2018-11, Vol.13 (21), p.3281-3284
Main Authors: Li, Yu‐Ting, Zhu, Yan, Tu, Guang‐Liang, Zhang, Jing‐Yu, Zhao, Ying‐Sheng
Format: Article
Language:English
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Summary:A highly efficient rhodium(III)‐catalyzed direct oxidative annulation of acrylic acid with alkynes to form α‐pyrones was developed. Various substituted acrylic acids were compatible in this transformation, affording the corresponding products in moderate to excellent yields under mild conditions. Pyrone is in the house! A highly efficient rhodium(III)‐catalyzed direct oxidative annulation of acrylic acid with alkynes to form α‐pyrones was developed. Various substituted acrylic acids were compatible in this transformation, affording the corresponding products in moderate to excellent yields under mild conditions.
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201801190