Valorization of poly(lactic acid) wastes via mechanical recycling: Improvement of the properties of the recycled polymer

Poly(lactic acid) (PLA) is a biobased polymer that represents one of the most interesting alternatives to fossil-fuel based polymers in food packaging applications. Most of the PLA used in food packaging is used only once and then discarded, even though the PLA types used in packaging have good prop...

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Bibliographic Details
Published in:Waste management & research 2019-02, Vol.37 (2), p.135-141
Main Authors: Beltrán, F.R., Barrio, I., Lorenzo, V., del Río, B., Martínez Urreaga, J., de la Orden, M.U.
Format: Article
Language:English
Subjects:
Acidic wastes
Aging
Alternative fuels
Diamond pyramid hardness
Environmental impact
Food packaging
Fossil fuels
Mechanical properties
Photochemicals
Polylactic acid
Polymers
Recyclability
Recycled materials
Recycling
Reprocessing
Thermal stability
Viscosity
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Summary:Poly(lactic acid) (PLA) is a biobased polymer that represents one of the most interesting alternatives to fossil-fuel based polymers in food packaging applications. Most of the PLA used in food packaging is used only once and then discarded, even though the PLA types used in packaging have good properties and stability. Therefore, it seems reasonable to consider the possibility of recycling the used polymer through a mechanical recycling process. The main aims of this work are to study the effect of the mechanical recycling on the properties of PLA and the usefulness of different upgrading methods to obtain recycled PLA with improved properties. A commercial type of PLA was subjected to accelerated thermal, photochemical and hydrolytic aging and then reprocessed. During reprocessing, aged PLA was blended with virgin PLA and a commercial chain extender was added. Results point out that recycling causes the degradation of PLA, and negatively affects the thermal stability and mechanical properties. However, addition of virgin PLA, and the chain extender, led to an increase of up to 9% in the intrinsic viscosity and 8% in the Vickers hardness of the recycled material. These results suggest that mechanically recycled PLA with improved performance can be obtained, a fact which might improve the recyclability of PLA and thus the environmental impact of this material.
ISSN:0734-242X
1096-3669
DOI:10.1177/0734242X18798448