An environmentally friendly method for the enantioseparation and determination of benalaxyl in tobacco and soil by ultra‐performance convergence chromatography with tandem mass spectrometry

For the purpose of chiral separation and determination of benalaxyl enantiomers in tobacco and soil, we developed a rapid, green, and sensitive method using ultra‐performance convergence chromatography with tandem mass spectrometry. The samples were extracted and purified by the quick, easy, cheap,...

Full description

Saved in:
Bibliographic Details
Published in:Journal of separation science 2018-11, Vol.41 (22), p.4233-4240
Main Authors: Yang, Fei, Tang, Gangling, Li, Zhonghao, Fan, Ziyan, Wang, Ying, Liu, Shanshan, Bian, Zhaoyang, Deng, Huimin
Format: Article
Language:English
Subjects:
Alanine - analogs & derivatives
Alanine - analysis
benalaxyl
Carbon dioxide
Chromatography
Chromatography, High Pressure Liquid
Column chromatography
Convergence
Enantiomers
enantioseparation
Ethanol
fungicide
Ions
Mass spectrometry
Molecular Conformation
Nicotiana - chemistry
Scientific imaging
Separation
Soil - chemistry
Spectroscopy
Stereoisomerism
Tandem Mass Spectrometry
Tobacco
ultra‐performance convergence chromatography
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:For the purpose of chiral separation and determination of benalaxyl enantiomers in tobacco and soil, we developed a rapid, green, and sensitive method using ultra‐performance convergence chromatography with tandem mass spectrometry. The samples were extracted and purified by the quick, easy, cheap, effective, rugged, and safe method before injection. The baseline separation was obtained on a chiral column in 5 min with carbon dioxide and ethanol as mobile phase. Separation parameters were optimized for the best separation efficiency. Under optimal conditions, the recoveries of both enantiomers were 77.1–98.4% with relative standard deviations
ISSN:1615-9306
1615-9314
DOI:10.1002/jssc.201800861