Assessing the performance of wastewater treatment with the combination of Fenton and ferrite process

• Published in: Environmental monitoring and assessment 2009-04, Vol.151 (1-4), p.251-258
• Main Authors: Lou, Jie-Chung, Huang, Yu-Jen
• Format: Article
• Language: English
• Subjects: Acids; Applied sciences; Atmospheric Protection/Air Quality Control/Air Pollution; Caustic soda; Chelating Agents - chemistry; Chemical precipitation; Earth and Environmental Science; Ecology; Ecotoxicology; Edetic Acid - chemistry; Effluent standards; Effluents; Environment; Environmental Management; Environmental monitoring; Exact sciences and technology; Ferric Compounds - chemistry; Heavy metals; Humans; Hydrogen peroxide; Hydrogen-Ion Concentration; Industrial Waste - analysis; Industrial wastes; Industrial wastewater; Industrial wastewaters; Ions; Leaching; Metal ions; Metals - analysis; Monitoring/Environmental Analysis; Oxidation; Oxidation-Reduction; Particle Size; Performance assessment; Pollution; Processes; Sewage - analysis; Sludge; Studies; Taiwan; Toxicity; Waste Disposal, Fluid - methods; Wastewater treatment; Wastewaters; Water Purification - instrumentation; Water Purification - methods; Water treatment; Water treatment and pollution
• ISSN: 0167-6369; 1573-2959
• DOI: 10.1007/s10661-008-0266-x

Industrial wastewater typically contains various metal ions. Traditional metal ion treatment processes such as chemical precipitation generate large volumes of toxic sludge which needs to be further solidified or disposed of. The ferrite process (FP), which is another effective approach of treating metal ion-containing wastewater, can crystallize metal ions into ferrites; the sludge easily precipitates, is stable and can be recycling. This investigation explores the feasibility of the Fenton process and the FP (FFP) for treating wastewater that contains metal ions. It considers one factor that adds noise to the FP, ethylenediaminetetraacetic acid, and establishes the optimum parameters of each procedure. The analytical results demonstrate that the proper conditions for Fenton process were pH = 2, [Fe 2+ ] = 10 −2  M, H 2 O 2 dosing rate = 5 × 10 −4  mol min −1 , reaction time = 12 min. For the proposed multi-stage FP, the preferred Fe 2+ dosage was 0.098 mol in each stage and the sludge met the toxicity characteristic leaching procedure standards. Following the FFP, the effluent water or the sludge easily met Taiwan’s standards. Finally, the SEM test demonstrated that size of the sludge particles was 50–110 nm.