N,O-Bidentate ligand-tunable copper(ii) complexes as a catalyst for Chan-Lam coupling reactions of arylboronic acids with 1H-imidazole derivatives

An efficient procedure for Chan-Lam coupling reactions of arylboronic acids with 1H-imidazole derivatives using N,O-bidentate ligand-tunable copper(ii) complexes as a catalyst under base-free conditions has been developed. This protocol features mild reaction conditions, high yields and compatibilit...

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Published in:Organic & biomolecular chemistry 2018-11, Vol.16 (46), p.8984-8988
Main Authors: Jia, Xuefeng, Peng, Pai
Format: Article
Language:English
Subjects:
Acids
Catalysis
Catalysts
Chemical bonds
Chemical reactions
Coordination compounds
Copper
Copper compounds
Coupling
Derivatives
Functional groups
Heterocyclic compounds
Imidazole
Ligands
NMR
Nuclear magnetic resonance
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Peng, Pai
description An efficient procedure for Chan-Lam coupling reactions of arylboronic acids with 1H-imidazole derivatives using N,O-bidentate ligand-tunable copper(ii) complexes as a catalyst under base-free conditions has been developed. This protocol features mild reaction conditions, high yields and compatibility with different functional groups, providing a direct and facile strategy for the construction of C-N bonds and synthesis of heterocyclic compounds.
doi_str_mv 10.1039/c8ob02254b
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source Royal Society of Chemistry
subjects Acids
Catalysis
Catalysts
Chemical bonds
Chemical reactions
Coordination compounds
Copper
Copper compounds
Coupling
Derivatives
Functional groups
Heterocyclic compounds
Imidazole
Ligands
NMR
Nuclear magnetic resonance
title N,O-Bidentate ligand-tunable copper(ii) complexes as a catalyst for Chan-Lam coupling reactions of arylboronic acids with 1H-imidazole derivatives
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