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Characterisation and attempted differentiation of European and extra-European olive oils using stable isotope ratio analysis

•2H/1H, 13C/12C, 18O/16O of bulk was combined with 13C/12C and 2H/1H of fatty acids.•Isotopic composition was used to distinguish EU and non EU extra virgin olive oils.•Application of Random Forest classification and model performance were evaluated. European law requires a designation of origin for...

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Bibliographic Details
Published in:Food chemistry 2019-03, Vol.276, p.782-789
Main Authors: Bontempo, Luana, Paolini, Mauro, Franceschi, Pietro, Ziller, Luca, García-González, Diego L., Camin, Federica
Format: Article
Language:English
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Summary:•2H/1H, 13C/12C, 18O/16O of bulk was combined with 13C/12C and 2H/1H of fatty acids.•Isotopic composition was used to distinguish EU and non EU extra virgin olive oils.•Application of Random Forest classification and model performance were evaluated. European law requires a designation of origin for virgin and extra virgin olive oils (at least in terms of EU/non-EU provenance). Stable isotope ratios have been successfully applied to determine the geographical origin of olive oils, but never to distinguish EU and non-EU oils. In this study 2H/1H, 13C/12C and 18O/16O ratios were analysed in bulk olive oils using Isotope Ratio Mass Spectrometry (IRMS) as well as 13C/12C and 2H/1H in the four main fatty acids (linoleic, oleic, palmitic and stearic acids) using IRMS coupled with GC. The isotopic composition of olive oils was successfully used to distinguish samples originating in the two areas. Specifically, when bulk data were combined with fatty acid isotopic data the differentiation power of the method improved clearly. This separation is due to the specific isotopic fingerprint of the individual countries making up the EU and non-EU samples.
ISSN:0308-8146
1873-7072
DOI:10.1016/j.foodchem.2018.10.077