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Characteristics of pipe corrosion scales in untreated water distribution system and effect on water quality in Peshawar, Pakistan
This study investigated the characteristics of iron corrosion scales in pipes at tube well, overhead tank, and consumers’ end in older untreated water distribution system in Peshawar city, Pakistan. Effect of water quality conditions on corrosion scales and that of scales on drinking water quality i...
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Published in: | Environmental science and pollution research international 2019-02, Vol.26 (6), p.5794-5803 |
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creator | Shams, Dilawar Farhan Islam, Saeed Shi, Baoyou Khan, Waliullah Gunawardana, Buddhika Saad, Maryam Qasim, Muhammad Javed, Haider Ali Afridi, Sahib Gul Naeem, Muhammad Khan, Gul Shahzada |
description | This study investigated the characteristics of iron corrosion scales in pipes at tube well, overhead tank, and consumers’ end in older untreated water distribution system in Peshawar city, Pakistan. Effect of water quality conditions on corrosion scales and that of scales on drinking water quality in such systems was also assessed by undertaking a comparison with new piped distribution systems. The scales were analyzed for chemical composition and morphology using X-ray diffraction (XRD), inductively coupled plasma (ICP), and a scanning electron microscope (SEM), while water quality was examined for physicochemical and biological characteristics. The main crystalline phases of corrosion scales were goethite, magnetite, siderite, and quartz. From tube well to consumers’ end, goethite increased from 36 up to 48%, quartz declined from 22 to 15%, while magnetite fluctuated and siderite disappeared. Elemental composition of scales showed the deposition of Zn, Al, Mn, Cr, Pb, Cu, As, and Cd with Zn (13.9 g/kg) and Al (3.6 g/kg) in highest proportion. The SEM analysis illustrated the presence of microbial communities indicating the formation of biofilms in the corrosion scales. The significant difference (
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doi_str_mv | 10.1007/s11356-018-04099-6 |
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P
< 0.05) in levels of dissolved oxygen (DO), Cl
−
, SiO
4
4−
, electrical conductivity (EC), SO
4
2−
, NO
3
−
, alkalinity, hardness, and trace metals between old (DS-O) and new piped systems indicated their role in corrosion scale formation/destabilization and the effect of scale dissolution on water quality. In DS-O, EC, Cu, and Mn were significantly higher (
P
< 0.05), whereas turbidity, EC, DO, and SiO
4
4−
significantly increased from source to consumers’ end implying a higher dissolution of scales and lowered corrosion rates in DS-O to utilize SiO
4
4−
and DO for iron oxidation.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-018-04099-6</identifier><identifier>PMID: 30613893</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Alkalinity ; Aluminum ; Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Bacterial corrosion ; Biofilms ; Cadmium ; Carbonates ; Chemical composition ; Chromium ; Consumers ; Copper ; Corrosion ; Corrosion effects ; Corrosion rate ; Destabilization ; Dissolution ; Dissolved oxygen ; Drinking water ; Drinking Water - chemistry ; Earth and Environmental Science ; Ecotoxicology ; Electrical conductivity ; Electrical resistivity ; Electron microscopes ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental science ; Ferric Compounds ; Ferrosoferric Oxide ; Goethite ; Heavy metals ; Iron ; Iron Compounds ; Magnetite ; Manganese ; Microbial activity ; Minerals ; Morphology ; Organic chemistry ; Oxidation ; Pakistan ; Quartz ; Research Article ; Scale (corrosion) ; Scanning electron microscopy ; Trace metals ; Turbidity ; Waste Water Technology ; Water ; Water distribution ; Water distribution systems ; Water engineering ; Water Management ; Water Pollutants, Chemical - analysis ; Water Pollution Control ; Water Quality ; Water Supply - methods ; Water Supply - statistics & numerical data ; X-Ray Diffraction</subject><ispartof>Environmental science and pollution research international, 2019-02, Vol.26 (6), p.5794-5803</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2019</rights><rights>Environmental Science and Pollution Research is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c441t-d48c4ae8a6826c77a3413e56fc02b04919cb02e01063a0c65ef98dca866ee4393</citedby><cites>FETCH-LOGICAL-c441t-d48c4ae8a6826c77a3413e56fc02b04919cb02e01063a0c65ef98dca866ee4393</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2188530920/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2188530920?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,11688,27924,27925,36060,36061,44363,74895</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30613893$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shams, Dilawar Farhan</creatorcontrib><creatorcontrib>Islam, Saeed</creatorcontrib><creatorcontrib>Shi, Baoyou</creatorcontrib><creatorcontrib>Khan, Waliullah</creatorcontrib><creatorcontrib>Gunawardana, Buddhika</creatorcontrib><creatorcontrib>Saad, Maryam</creatorcontrib><creatorcontrib>Qasim, Muhammad</creatorcontrib><creatorcontrib>Javed, Haider Ali</creatorcontrib><creatorcontrib>Afridi, Sahib Gul</creatorcontrib><creatorcontrib>Naeem, Muhammad</creatorcontrib><creatorcontrib>Khan, Gul Shahzada</creatorcontrib><title>Characteristics of pipe corrosion scales in untreated water distribution system and effect on water quality in Peshawar, Pakistan</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>This study investigated the characteristics of iron corrosion scales in pipes at tube well, overhead tank, and consumers’ end in older untreated water distribution system in Peshawar city, Pakistan. Effect of water quality conditions on corrosion scales and that of scales on drinking water quality in such systems was also assessed by undertaking a comparison with new piped distribution systems. The scales were analyzed for chemical composition and morphology using X-ray diffraction (XRD), inductively coupled plasma (ICP), and a scanning electron microscope (SEM), while water quality was examined for physicochemical and biological characteristics. The main crystalline phases of corrosion scales were goethite, magnetite, siderite, and quartz. From tube well to consumers’ end, goethite increased from 36 up to 48%, quartz declined from 22 to 15%, while magnetite fluctuated and siderite disappeared. Elemental composition of scales showed the deposition of Zn, Al, Mn, Cr, Pb, Cu, As, and Cd with Zn (13.9 g/kg) and Al (3.6 g/kg) in highest proportion. The SEM analysis illustrated the presence of microbial communities indicating the formation of biofilms in the corrosion scales. The significant difference (
P
< 0.05) in levels of dissolved oxygen (DO), Cl
−
, SiO
4
4−
, electrical conductivity (EC), SO
4
2−
, NO
3
−
, alkalinity, hardness, and trace metals between old (DS-O) and new piped systems indicated their role in corrosion scale formation/destabilization and the effect of scale dissolution on water quality. In DS-O, EC, Cu, and Mn were significantly higher (
P
< 0.05), whereas turbidity, EC, DO, and SiO
4
4−
significantly increased from source to consumers’ end implying a higher dissolution of scales and lowered corrosion rates in DS-O to utilize SiO
4
4−
and DO for iron oxidation.</description><subject>Alkalinity</subject><subject>Aluminum</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Bacterial corrosion</subject><subject>Biofilms</subject><subject>Cadmium</subject><subject>Carbonates</subject><subject>Chemical composition</subject><subject>Chromium</subject><subject>Consumers</subject><subject>Copper</subject><subject>Corrosion</subject><subject>Corrosion effects</subject><subject>Corrosion rate</subject><subject>Destabilization</subject><subject>Dissolution</subject><subject>Dissolved oxygen</subject><subject>Drinking water</subject><subject>Drinking Water - chemistry</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Electrical conductivity</subject><subject>Electrical resistivity</subject><subject>Electron microscopes</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental science</subject><subject>Ferric Compounds</subject><subject>Ferrosoferric Oxide</subject><subject>Goethite</subject><subject>Heavy metals</subject><subject>Iron</subject><subject>Iron Compounds</subject><subject>Magnetite</subject><subject>Manganese</subject><subject>Microbial activity</subject><subject>Minerals</subject><subject>Morphology</subject><subject>Organic chemistry</subject><subject>Oxidation</subject><subject>Pakistan</subject><subject>Quartz</subject><subject>Research Article</subject><subject>Scale (corrosion)</subject><subject>Scanning electron microscopy</subject><subject>Trace metals</subject><subject>Turbidity</subject><subject>Waste Water Technology</subject><subject>Water</subject><subject>Water distribution</subject><subject>Water distribution systems</subject><subject>Water engineering</subject><subject>Water Management</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water Pollution Control</subject><subject>Water Quality</subject><subject>Water Supply - methods</subject><subject>Water Supply - statistics & numerical data</subject><subject>X-Ray Diffraction</subject><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>M0C</sourceid><recordid>eNp9kc1u3CAURlHUqpmmfYEsIqRuuqjbi8EYltGof1KkZtGu0R18nZB47AlgRbPsm5eJk0bqohuQ4Hwf6B7GTgV8FADtpySEbHQFwlSgwNpKH7GV0EJVrbL2BVuBVaoSUqlj9jqlG4AabN2-YscStJDGyhX7vb7GiD5TDCkHn_jU813YEfdTjFMK08iTx4ESDyOfxxwJM3X8vqyRdyUTw2bOD9g-ZdpyHDtOfU8-83K4cHczDiHvDxWXlK7xHuMHfom3JY7jG_ayxyHR28f9hP368vnn-lt18ePr9_X5ReWVErnqlPEKyaA2tfZti1IJSY3uPdQbUFZYv4GaQICWCF431FvTeTRaEylp5Ql7v_Tu4nQ3U8puG5KnYcCRpjm5WmjVNFroA_ruH_RmmuNYflcoYxpZxgiFqhfKl0GlSL3bxbDFuHcC3EGQWwS5Isg9CHK6hM4eq-fNlrq_kScjBZALkMrVeEXx-e3_1P4BiXedDg</recordid><startdate>20190201</startdate><enddate>20190201</enddate><creator>Shams, Dilawar Farhan</creator><creator>Islam, Saeed</creator><creator>Shi, Baoyou</creator><creator>Khan, Waliullah</creator><creator>Gunawardana, Buddhika</creator><creator>Saad, Maryam</creator><creator>Qasim, Muhammad</creator><creator>Javed, Haider Ali</creator><creator>Afridi, Sahib Gul</creator><creator>Naeem, Muhammad</creator><creator>Khan, Gul Shahzada</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>7WY</scope><scope>7WZ</scope><scope>7X7</scope><scope>7XB</scope><scope>87Z</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8FL</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FRNLG</scope><scope>FYUFA</scope><scope>F~G</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K60</scope><scope>K6~</scope><scope>K9.</scope><scope>L.-</scope><scope>M0C</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7N</scope><scope>P64</scope><scope>PATMY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7X8</scope></search><sort><creationdate>20190201</creationdate><title>Characteristics of pipe corrosion scales in untreated water distribution system and effect on water quality in Peshawar, Pakistan</title><author>Shams, Dilawar Farhan ; Islam, Saeed ; Shi, Baoyou ; Khan, Waliullah ; Gunawardana, Buddhika ; Saad, Maryam ; Qasim, Muhammad ; Javed, Haider Ali ; Afridi, Sahib Gul ; Naeem, Muhammad ; Khan, Gul Shahzada</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c441t-d48c4ae8a6826c77a3413e56fc02b04919cb02e01063a0c65ef98dca866ee4393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Alkalinity</topic><topic>Aluminum</topic><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Bacterial corrosion</topic><topic>Biofilms</topic><topic>Cadmium</topic><topic>Carbonates</topic><topic>Chemical composition</topic><topic>Chromium</topic><topic>Consumers</topic><topic>Copper</topic><topic>Corrosion</topic><topic>Corrosion effects</topic><topic>Corrosion rate</topic><topic>Destabilization</topic><topic>Dissolution</topic><topic>Dissolved oxygen</topic><topic>Drinking water</topic><topic>Drinking Water - chemistry</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Electrical conductivity</topic><topic>Electrical resistivity</topic><topic>Electron microscopes</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental science</topic><topic>Ferric Compounds</topic><topic>Ferrosoferric Oxide</topic><topic>Goethite</topic><topic>Heavy metals</topic><topic>Iron</topic><topic>Iron Compounds</topic><topic>Magnetite</topic><topic>Manganese</topic><topic>Microbial activity</topic><topic>Minerals</topic><topic>Morphology</topic><topic>Organic chemistry</topic><topic>Oxidation</topic><topic>Pakistan</topic><topic>Quartz</topic><topic>Research Article</topic><topic>Scale (corrosion)</topic><topic>Scanning electron microscopy</topic><topic>Trace metals</topic><topic>Turbidity</topic><topic>Waste Water Technology</topic><topic>Water</topic><topic>Water distribution</topic><topic>Water distribution systems</topic><topic>Water engineering</topic><topic>Water Management</topic><topic>Water Pollutants, Chemical - analysis</topic><topic>Water Pollution Control</topic><topic>Water Quality</topic><topic>Water Supply - methods</topic><topic>Water Supply - statistics & numerical data</topic><topic>X-Ray Diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shams, Dilawar Farhan</creatorcontrib><creatorcontrib>Islam, Saeed</creatorcontrib><creatorcontrib>Shi, Baoyou</creatorcontrib><creatorcontrib>Khan, Waliullah</creatorcontrib><creatorcontrib>Gunawardana, Buddhika</creatorcontrib><creatorcontrib>Saad, Maryam</creatorcontrib><creatorcontrib>Qasim, Muhammad</creatorcontrib><creatorcontrib>Javed, Haider Ali</creatorcontrib><creatorcontrib>Afridi, Sahib Gul</creatorcontrib><creatorcontrib>Naeem, Muhammad</creatorcontrib><creatorcontrib>Khan, Gul Shahzada</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>ABI/INFORM Collection</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>ProQuest_Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Public Health Database (Proquest)</collection><collection>Technology Research Database</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>Business Premium Collection (Alumni)</collection><collection>Health Research Premium Collection</collection><collection>ABI/INFORM Global (Corporate)</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Global</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>PML(ProQuest Medical Library)</collection><collection>Science Database (ProQuest)</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environmental Science Database</collection><collection>One Business (ProQuest)</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shams, Dilawar Farhan</au><au>Islam, Saeed</au><au>Shi, Baoyou</au><au>Khan, Waliullah</au><au>Gunawardana, Buddhika</au><au>Saad, Maryam</au><au>Qasim, Muhammad</au><au>Javed, Haider Ali</au><au>Afridi, Sahib Gul</au><au>Naeem, Muhammad</au><au>Khan, Gul Shahzada</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characteristics of pipe corrosion scales in untreated water distribution system and effect on water quality in Peshawar, Pakistan</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2019-02-01</date><risdate>2019</risdate><volume>26</volume><issue>6</issue><spage>5794</spage><epage>5803</epage><pages>5794-5803</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>This study investigated the characteristics of iron corrosion scales in pipes at tube well, overhead tank, and consumers’ end in older untreated water distribution system in Peshawar city, Pakistan. Effect of water quality conditions on corrosion scales and that of scales on drinking water quality in such systems was also assessed by undertaking a comparison with new piped distribution systems. The scales were analyzed for chemical composition and morphology using X-ray diffraction (XRD), inductively coupled plasma (ICP), and a scanning electron microscope (SEM), while water quality was examined for physicochemical and biological characteristics. The main crystalline phases of corrosion scales were goethite, magnetite, siderite, and quartz. From tube well to consumers’ end, goethite increased from 36 up to 48%, quartz declined from 22 to 15%, while magnetite fluctuated and siderite disappeared. Elemental composition of scales showed the deposition of Zn, Al, Mn, Cr, Pb, Cu, As, and Cd with Zn (13.9 g/kg) and Al (3.6 g/kg) in highest proportion. The SEM analysis illustrated the presence of microbial communities indicating the formation of biofilms in the corrosion scales. The significant difference (
P
< 0.05) in levels of dissolved oxygen (DO), Cl
−
, SiO
4
4−
, electrical conductivity (EC), SO
4
2−
, NO
3
−
, alkalinity, hardness, and trace metals between old (DS-O) and new piped systems indicated their role in corrosion scale formation/destabilization and the effect of scale dissolution on water quality. In DS-O, EC, Cu, and Mn were significantly higher (
P
< 0.05), whereas turbidity, EC, DO, and SiO
4
4−
significantly increased from source to consumers’ end implying a higher dissolution of scales and lowered corrosion rates in DS-O to utilize SiO
4
4−
and DO for iron oxidation.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>30613893</pmid><doi>10.1007/s11356-018-04099-6</doi><tpages>10</tpages></addata></record> |
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language | eng |
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source | ABI/INFORM Global; Springer Link |
subjects | Alkalinity Aluminum Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Bacterial corrosion Biofilms Cadmium Carbonates Chemical composition Chromium Consumers Copper Corrosion Corrosion effects Corrosion rate Destabilization Dissolution Dissolved oxygen Drinking water Drinking Water - chemistry Earth and Environmental Science Ecotoxicology Electrical conductivity Electrical resistivity Electron microscopes Environment Environmental Chemistry Environmental Health Environmental science Ferric Compounds Ferrosoferric Oxide Goethite Heavy metals Iron Iron Compounds Magnetite Manganese Microbial activity Minerals Morphology Organic chemistry Oxidation Pakistan Quartz Research Article Scale (corrosion) Scanning electron microscopy Trace metals Turbidity Waste Water Technology Water Water distribution Water distribution systems Water engineering Water Management Water Pollutants, Chemical - analysis Water Pollution Control Water Quality Water Supply - methods Water Supply - statistics & numerical data X-Ray Diffraction |
title | Characteristics of pipe corrosion scales in untreated water distribution system and effect on water quality in Peshawar, Pakistan |
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