Efficient and controllable alcoholysis of Kraft lignin catalyzed by porous zeolite-supported nickel-copper catalyst

• Published in: Bioresource technology 2019-03, Vol.276, p.310-317
• Main Authors: Kong, Liping, Liu, Chunze, Gao, Ji, Wang, Yuanyuan, Dai, Liyi
• Format: Article
• Language: English
• Subjects: Alcoholysis; Catalyst structure; Cycloalkanes; Kraft lignin; Ni-Cu/H-Beta
• ISSN: 0960-8524; 1873-2976
• DOI: 10.1016/j.biortech.2019.01.015

[Display omitted] •Kraft lignin depolymerization was conducted over Ni-Cu bifunctional catalyst.•Higher lignin conversion and oil yield were obtained by Ni-Cu/H-Beta catalyst.•The composition of liquid products was influenced by the structure of catalyst.•Isopropanol was most favorable for the hydrogenolysis of lignin. The alcoholysis of Kraft lignin was catalyzed by bimetallic Ni-Cu supported on H-Beta, HZSM-5, MAS-7, MCM-41 and SAPO-11 zeolite materials in isopropanol solvent. Results showed that a higher bio-oil yield of 98.80 wt% and monomer yield of 50.83 wt% without obvious char were achieved at 330 °C for 3 h over Ni-Cu/H-Beta catalyst. Isopropanol was found to be more effective in H2 generation and facilitated to the hydrodeoxygenation of lignin-derived phenolic compounds. Moreover, the composition of liquid products was also influenced by the acidity and pore structure of catalyst. The superior cycloalkanes yield was produced over Ni-Cu/H-Beta with larger pore size and more acidity. In contrast, a large number of cyclic ketones/alcohols and alkanes were obtained over other zeolites supported catalysts with smaller pore size and less acid content. Besides, the temperature, time and solvent effect on the lignin depolymerization were also researched.