Modulating ICT emission: a new strategy to manipulate the CPL sign in chiral emitters

A new strategy to manipulate the circularly polarized luminescence (CPL) handedness in chiral emitters, based on modulating the population of an emissive ICT state, is proposed. Such a strategy is particularly interesting for conformationally rigid and non-aggregating chiral organic emitters, openin...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2019-01, Vol.55 (11), p.1631-1634
Main Authors: Jiménez, Josué, Moreno, Florencio, Maroto, Beatriz L, Cabreros, Trevor A, Huy, Angelenia S, Muller, Gilles, Bañuelos, Jorge, de la Moya, Santiago
Format: Article
Language:English
Subjects:
Circular polarization
Emitters
Organic chemistry
Strategy
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Summary:A new strategy to manipulate the circularly polarized luminescence (CPL) handedness in chiral emitters, based on modulating the population of an emissive ICT state, is proposed. Such a strategy is particularly interesting for conformationally rigid and non-aggregating chiral organic emitters, opening up new perspectives for the development of CPL applications based on organic molecules. A new strategy to manipulate the CPL sign is described.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c8cc09401b