High-performance porous biochar from the pyrolysis of natural and renewable seaweed (Gelidiella acerosa) and its application for the adsorption of methylene blue

• Published in: Bioresource technology 2019-04, Vol.278, p.159-164
• Main Authors: Ahmed, M.J., Okoye, P.U., Hummadi, E.H., Hameed, B.H.
• Format: Article
• Language: English
• Subjects: Adsorption; Kinetics; Porous biochar; Pyrolysis; Seaweed
• ISSN: 0960-8524; 1873-2976
• DOI: 10.1016/j.biortech.2019.01.054

[Display omitted] •High performance biochar was prepared from seaweed.•Favorable pore characteristics of 926.39 m2/g and 0.57 cm3/g were obtained.•Adsorption behaviors were detected for methylene blue removal.•Maximum MB uptake of 512.67 mg/g was achieved at 30 °C. A high-performance porous biochar adsorbent prepared by facile thermal pyrolysis of seaweed (Gelidiella acerosa) is reported. The textural characteristics of the prepared seaweed biochar (SWBC) and the performance in the adsorption of methylene blue (MB) dye were evaluated. The batch experiment for the adsorption of MB was conducted under different parameters, such as temperature, pH, and initial concentration of MB in the range of 25–400 mg/L. The developed SWBC exhibited a relatively high surface area, average pore size, and pore volume of 926.39 m2/g, 2.45 nm, and 0.57 cm3/g, respectively. The high surface area and pristine mineral constituents of the biochar promoted a high adsorption capacity of 512.67 mg/g of MB at 30 °C. The adsorption isotherm and kinetics data best fitted the Langmuir and pseudo-second-order equations. The results indicate that SWBC is efficient for MB adsorption and could be a potential adsorbent for wastewater treatment.