Use of cellulose acetate/polyphenylsulfone derivatives to fabricate ultrafiltration hollow fiber membranes for the removal of arsenic from drinking water

Cellulose acetate (CA) and cellulose acetate phthalate (CAP) were used as additives (1 wt%, 3 wt%, and 5 wt%) to prepare polyphenylsulfone (PPSU) hollow fiber membranes. Prepared hollow fiber membranes were characterized by surface morphology using scanning electron microscopy (SEM), surface roughne...

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Bibliographic Details
Published in:International journal of biological macromolecules 2019-05, Vol.129, p.715-727
Main Authors: Kumar, Mithun, RaoT, Somasekhara, Isloor, Arun M., Ibrahim, G.P. Syed, Inamuddin, Ismail, Norafiqah, Ismail, Ahmed Fauzi, Asiri, Abdullah M.
Format: Article
Language:English
Subjects:
Arsenic - chemistry
Arsenic - isolation & purification
Arsenic removal
Cellulose - analogs & derivatives
Cellulose - chemistry
Cellulose acetate
Cellulose acetate phthalate
Drinking Water - chemistry
Hydrophilicity
Hydrophobic and Hydrophilic Interactions
Membranes, Artificial
Molecular Weight
Permeability
Polyphenylsulfone
Porosity
Surface Properties
Ultrafiltration
Ultrafiltration - methods
Water Pollutants, Chemical - chemistry
Water Pollutants, Chemical - isolation & purification
Water Purification - methods
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Summary:Cellulose acetate (CA) and cellulose acetate phthalate (CAP) were used as additives (1 wt%, 3 wt%, and 5 wt%) to prepare polyphenylsulfone (PPSU) hollow fiber membranes. Prepared hollow fiber membranes were characterized by surface morphology using scanning electron microscopy (SEM), surface roughness by atomic force microscopy (AFM), the surface charge of the membrane was analyzed by zeta potential measurement, hydrophilicity by contact angle measurement and the functional groups by fourier transform infrared spectroscopy (FTIR). Fouling resistant nature of the prepared hollow fiber membranes was evaluated by bovine serum albumin (BSA) and molecular weight cutoff was investigated using polyethylene glycol (PEG). By total organic carbon (TOC), the percentage rejection of PEG was found to be 14,489 Da. It was found that the hollow fiber membrane prepared by the addition of 5 wt% of CAP in PPSU confirmed increased arsenic removal from water as compared to hollow fiber membrane prepared by 5 wt% of CA in PPSU. The removal percentages of arsenic with CA-5 and CAP-5 hollow fiber membrane was 34% and 41% with arsenic removal permeability was 44.42 L/m2h bar and 40.11 L/m2h bar respectively. The increased pure water permeability for CA-5 and CAP-5 hollow fiber membrane was 61.47 L/m2h bar and 69.60 L/m2 h bar, respectively.
ISSN:0141-8130
1879-0003
DOI:10.1016/j.ijbiomac.2019.02.017