An isolable iron(ii) bis(supersilyl) complex as an effective catalyst for reduction reactions

An isolable 14-electron iron bis(supersilyl) complex, Fe[Si(SiMe3)3]2(THF)2, was successfully synthesized from the reaction of FeBr2 with K[Si(SiMe3)3] and its structure was unambiguously determined by single-crystal X-ray diffraction analysis. The complex is coordinatively unsaturated and exhibits...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2019, Vol.48 (9), p.2891-2895
Main Authors: Arata, Shogo, Sunada, Yusuke
Format: Article
Language:English
Subjects:
Carbonyl compounds
Carbonyls
Catalysis
Catalytic activity
Chemical reduction
Chemical synthesis
Crystal structure
Crystallography
Crystals
Hydrosilylation
Iron
Single crystals
X-ray diffraction
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description An isolable 14-electron iron bis(supersilyl) complex, Fe[Si(SiMe3)3]2(THF)2, was successfully synthesized from the reaction of FeBr2 with K[Si(SiMe3)3] and its structure was unambiguously determined by single-crystal X-ray diffraction analysis. The complex is coordinatively unsaturated and exhibits high catalytic activity toward the hydrosilylation of carbonyl compounds and the reductive silylation of dinitrogen.
doi_str_mv 10.1039/c9dt00116f
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source Royal Society of Chemistry
subjects Carbonyl compounds
Carbonyls
Catalysis
Catalytic activity
Chemical reduction
Chemical synthesis
Crystal structure
Crystallography
Crystals
Hydrosilylation
Iron
Single crystals
X-ray diffraction
title An isolable iron(ii) bis(supersilyl) complex as an effective catalyst for reduction reactions
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