Pentacarbonylmethylmanganese() as a synthon for Mn() pincer catalysts

Mn( i ) complexes that enable metal-ligand cooperative substrate activation catalyze a range of transformations. Use of MeMn(CO) 5 as a synthon in place of typical Mn(CO) 5 Br was explored and found to be quite versatile, generating catalytically active species in situ by activation of O-H, N-H, and...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2019-04, Vol.48 (14), p.4467-447
Main Authors: Kadassery, Karthika J, Lacy, David C
Format: Article
Language:English
Subjects:
Activation
Coordination compounds
Substrates
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Summary:Mn( i ) complexes that enable metal-ligand cooperative substrate activation catalyze a range of transformations. Use of MeMn(CO) 5 as a synthon in place of typical Mn(CO) 5 Br was explored and found to be quite versatile, generating catalytically active species in situ by activation of O-H, N-H, and even C-H bonds. MeMn(CO) 5 efficiently forms active Mn( i ) pincer catalysts under base-free catalytically relevant conditions.
ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt00529c