Regulating Bulk‐Heterojunction Molecular Orientations through Surface Free Energy Control of Hole‐Transporting Layers for High‐Performance Organic Solar Cells

• Published in: Advanced materials (Weinheim) 2019-04, Vol.31 (17), p.e1806921-n/a
• Main Authors: Wang, Jianqiu, Zheng, Zhong, Zhang, Dongyang, Zhang, Jianqi, Zhou, Jiyu, Liu, Jingchong, Xie, Shenkun, Zhao, Yong, Zhang, Yuan, Wei, Zhixiang, Hou, Jianhui, Tang, Zhiyong, Zhou, Huiqiong
• Format: Article
• Language: English
• Subjects: Carrier mobility; Carrier transport; Current carriers; Energy conversion efficiency; Free energy; Fullerenes; Heterojunctions; interfacial layers; Interfacial properties; Materials science; Morphology; Organic chemistry; organic solar cells; Photovoltaic cells; Polystyrene resins; power conversion efficiency; Sodium salts; Solar cells; Sulfonic acid; surface free energy; Surface properties
• ISSN: 0935-9648; 1521-4095
• DOI: 10.1002/adma.201806921

Interface properties are of critical importance for high‐performance bulk‐heterojunction (BHJ) organic solar cells (OSCs). Here, a universal interface approach to tune the surface free energy (γS) of hole‐transporting layers (HTLs) in a wide range through introducing poly(styrene sulfonic acid) sodium salts or nickel formate dihydrate into poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is reported. Based on the optimal γS of HTLs and thus improved face‐on molecular ordering in BHJs, enhanced fill factor and power conversion efficiencies in both fullerene and nonfullerene OSCs are achieved, which is attributed to the increased charge carrier mobility and sweepout with reduced recombination. It is found that the face‐on orientation‐preferred BHJs (PBDB‐TF:PC71BM, PBDB‐T:PC71BM, and PBDB‐TF:IT‐4F) favor HTLs with higher γS while the edge‐on orientation‐preferred BHJs (PDCDT:PC71BM, P3HT:PC71BM and PDCBT:ITIC) are partial to HTLs with lower γS. Based on the surface property–morphology–device performance correlations, a suggestion to select a suitable HTL in terms of γS for a specific BHJ with favored molecular arrangement is provided. This work enriches the fundamental understandings on the interface characteristics and morphological control toward high‐efficiency OSCs based on a wide range of BHJ materials. The molecular orientation and charge extraction of PEDOT:PSS‐based hole‐transporting layers are effectively modulated through fine tuning of the surface energy by introducing poly(styrene sulfonic acid) sodium salts or nickel formate dihydrate, which boosts the fill factor and eventual efficiency of organic solar cells based on fullerene and nonfullerene acceptors.