Radical Umpolung: Efficient Options for the Synthesis of 1,4‐Dicarbonyl Compounds

Radical developments: Photochemical/secondary amine dual catalysis has proven to be an efficient strategy for radical umpolung reactions. Two new processes provide an elegant solution to a long‐standing chemoselectivity problem for the synthesis of 1,4‐dicarbonyl compounds.

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2019-05, Vol.58 (20), p.6488-6490
Main Authors: Chen, Xiang‐Yu, Enders, Dieter
Format: Article
Language:English
Subjects:
Carbonyl compounds
Catalysis
dicarbonyl compounds
organocatalysis
photocatalysis
Photochemicals
Stetter reaction
Synthesis
umpolung
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Summary:Radical developments: Photochemical/secondary amine dual catalysis has proven to be an efficient strategy for radical umpolung reactions. Two new processes provide an elegant solution to a long‐standing chemoselectivity problem for the synthesis of 1,4‐dicarbonyl compounds.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201902132