35 Cl NQR frequency and spin lattice relaxation study in 3,4-dichloronitrobenzene as a function of temperature and pressure

Cl NQR frequency and spin lattice relaxation time in 3,4-dichloronitrobenzene have been measured as a function of temperature and pressure. Two NQR signals were observed in the temperature range 77 to 300 K and pressure up to 5.1 kbar at 300 K. The contributions to the relaxation from the torsional...

Full description

Saved in:
Bibliographic Details
Published in:Magnetic resonance in chemistry 2019-08, Vol.57 (8), p.499-505
Main Authors: Ramu, Loganathan, Kuppan, Narendra, Ramesh, Keralapura Parthasarathy, Chandramani, Rattihalli, Ramananda, Daivagna
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Cl NQR frequency and spin lattice relaxation time in 3,4-dichloronitrobenzene have been measured as a function of temperature and pressure. Two NQR signals were observed in the temperature range 77 to 300 K and pressure up to 5.1 kbar at 300 K. The contributions to the relaxation from the torsional motion of the molecule and reorientational motion of the nitro group have been analyzed on the basis of the Woessner and Gutowsky model. The temperature dependence of the average torsional lifetimes of the molecules, transition probabilities, and the activation energy for the reorientation of the nitro group was estimated. The pressure dependence of the NQR frequency in 3,4-Dichloronitrobenzene shows a nonlinear increase in NQR frequency with increase in pressure, indicating increased contribution from the static effects at higher pressures. A thermodynamic analysis of the data was carried out to determine the constant-volume temperature coefficients of the NQR frequency. The spin-lattice relaxation was found to be weakly dependent on pressure.
ISSN:0749-1581
1097-458X
DOI:10.1002/mrc.4881