Synthesis of amino-functionalized bentonite/CoFe2O4@MnO2 magnetic recoverable nanoparticles for aqueous Cd2+ removal

• Published in: The Science of the total environment 2019-09, Vol.682, p.505-513
• Main Authors: Zhou, Guangzhu, Wang, Yue, Zhou, Runsheng, Wang, Cuizhen, Jin, Yuqin, Qiu, Jun, Hua, Chunyu, Cao, Yiyun
• Format: Article
• Language: English
• Subjects: Adsorption; Amino-functionalization; Bentonite; Cadmium; Magnetic; MnO2
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2019.05.218

Magnetic nano-composite materials have been attracting considerable attention due to their unique properties and versatile applications. In this study, a novel magnetic amino-functionalized conjugate adsorbent, named as bentonite/CoFe2O4@MnO2-NH2 (BCFMNs), was synthesized by combining APTES and MnO2 with magnetic bentonite. XRD, FT-IR, SEM, EDS, TEM, and VSM techniques were used to characterize its structure and magnetic properties. Results were in indicative of productive synthesis, well-defined architecture and satisfactory magnetism. BET examinations illustrated 84.97m2/g of specific surface area, 0.15cm3/g of pore volume and 7.02nm average pore size. The effect parameters such as adsorbent dosage, contact time, initial concentration and ion selectivity and recycling were evaluated and optimized systematically. Also, the metal concentrations were measured by ICP-MS spectrometer. The feasibility of the BCFMNs for removal of Cd2+ from aqueous solution was also evaluated by adsorption experiments with the maximal adsorption efficiency for Cd2+ up to 98.88%. Cd2+ adsorption could be interpreted by the Langmuir adsorption isotherm and the maximum adsorption capacity was 115.79mg/g. The results revealed that the adsorbent still had higher selectivity of Cd2+ removal even in the presence of high concentration coexisting cations. The as-prepared magnetic conjugate adsorbent could be recycled by taking advantage of its magnetic properties. The distinctive structure of BCFMNs and its excellent adsorption performance of cadmium reflects its prospective application in water treatment. [Display omitted] •Solvothermally synthesized amino-functionalized magnetic bentonite/CoFe2O4@MnO2•Adsorbent has high sorption and kinetic performances for potential application.•Effectively adsorbed Cd2+ from solution with high amount of coexisting cations