High‐Temperature Reversible Phase‐Transition Behavior, Switchable Dielectric and Second Harmonic Generation Response of Two Homochiral Crown Ether Clathrates

Crowning achievement: Two homochiral crown ether clathrates were synthesized which undergo high‐temperature reversible phase transition. In addition, second harmonic generation (SHG) responses and abnormal dielectric property further confirm the reversible phase transitions and symmetry breaking beh...

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Bibliographic Details
Published in:Chemistry, an Asian journal an Asian journal, 2019-07, Vol.14 (13), p.2203-2209
Main Authors: Fan, Xiao‐Wei, Liu, Yi, Tang, Yun‐Zhi, Wei, Wen‐Juan, Zhang, Jian‐Chen, Luo, Zi‐Yu, Wang, Chang‐Feng, Tan, Yu‐Hui
Format: Article
Language:English
Subjects:
Broken symmetry
Chemistry
Clathrates
Crown ethers
Dielectric properties
Dielectric switches
Homochiral
Phase transitions
Reversible phase transition
Second harmonic generation
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Summary:Crowning achievement: Two homochiral crown ether clathrates were synthesized which undergo high‐temperature reversible phase transition. In addition, second harmonic generation (SHG) responses and abnormal dielectric property further confirm the reversible phase transitions and symmetry breaking behaviors of the structures.
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201900512