Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity. A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2019, Vol.55 (47), p.6799-682
Main Authors: Zinser, Caroline M, Nahra, Fady, Falivene, Laura, Brill, Marcel, Cordes, David B, Slawin, Alexandra M. Z, Cavallo, Luigi, Cazin, Catherine S. J, Nolan, Steven P
Format: Article
Language:English
Subjects:
Crystallography
Gold
Reactivity
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Summary:A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity. A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc03171e