Efficient modulation of photoluminescence by hydrogen bonding interactions between inorganic [MnBr 4 ] 2- anions and organic cations

The different hydrogen bond interactions in two organic-inorganic hybrid manganese halide compounds, namely [A]2[MnBr4] (A = N-butyl-N-methylpyrrolidinium ([P14]+) for (1) and N-butyl-N-methylpiperidinium ([PP14]+) for (2)), lead to distinct photoluminescence quantum yields (81% for 1; 55% for 2). F...

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Published in:Chemical communications (Cambridge, England) England), 2019-06, Vol.55 (51), p.7303-7306
Main Authors: Gong, Liao-Kuo, Hu, Qian-Qian, Huang, Fu-Quan, Zhang, Zhi-Zhuan, Shen, Nan-Nan, Hu, Bing, Song, Ying, Wang, Ze-Ping, Du, Ke-Zhao, Huang, Xiao-Ying
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Language:English
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Crystallography
Hydrogen bonding
Hydrogen bonds
Manganese
Photoluminescence
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cited_by cdi_FETCH-LOGICAL-c1601-7a542773f73cff38f13768e7e256db8c0fcf8efdfc256e8fa9585a06a994a5dd3
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container_issue 51
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container_title Chemical communications (Cambridge, England)
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creator Gong, Liao-Kuo
Hu, Qian-Qian
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Hu, Bing
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Wang, Ze-Ping
Du, Ke-Zhao
Huang, Xiao-Ying
description The different hydrogen bond interactions in two organic-inorganic hybrid manganese halide compounds, namely [A]2[MnBr4] (A = N-butyl-N-methylpyrrolidinium ([P14]+) for (1) and N-butyl-N-methylpiperidinium ([PP14]+) for (2)), lead to distinct photoluminescence quantum yields (81% for 1; 55% for 2). Further applications of luminescent 1 are also developed.
doi_str_mv 10.1039/C9CC03038G
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Crystallography
Hydrogen bonding
Hydrogen bonds
Manganese
Photoluminescence
title Efficient modulation of photoluminescence by hydrogen bonding interactions between inorganic [MnBr 4 ] 2- anions and organic cations
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