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Evaluation of hydroxyapatite/poly(acrylamide-acrylic acid) for sorptive removal of strontium ions from aqueous solution

A composite polymer, hydroxyapatite/poly(acrylamide-acrylic acid), was synthesized by gamma-induced polymerization. The factors affecting the sorption process were evaluated. The removal increased with time and achieved equilibrium after 1 h for all initial concentration ranges (10–50 mg/L). The hig...

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Published in:Environmental science and pollution research international 2019-09, Vol.26 (25), p.25641-25655
Main Authors: Hassan, Hisham Soliman, El-Kamash, Ahmed Mohamed, Ibrahim, Haneen Abdel-Salam
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description A composite polymer, hydroxyapatite/poly(acrylamide-acrylic acid), was synthesized by gamma-induced polymerization. The factors affecting the sorption process were evaluated. The removal increased with time and achieved equilibrium after 1 h for all initial concentration ranges (10–50 mg/L). The highest removal of Sr(II) was achieved using 50 mg/L at pH 6. The sorption process was found to follow a pseudo-first-order mechanism. The equilibrium data are best described by the Langmuir model, with a monolayer capacity of 53.59 mg/g. The values of thermodynamic parameters indicate that the sorption process is endothermic ( ΔH > 0), increases randomness ( ΔS > 0) and is spontaneous ( ΔG < 0). The results imply that the composite could be used as a promising low-cost material for the removal of radionuclides from radioactive waste.
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subjects Acrylamide
Acrylamide - chemistry
Acrylates - chemistry
Acrylic acid
Acrylic Resins - chemistry
Acrylics
Aquatic Pollution
Aqueous solutions
Atmospheric Protection/Air Quality Control/Air Pollution
Composite materials
composite polymers
Durapatite - chemistry
Earth and Environmental Science
Ecotoxicology
Endothermic reactions
endothermy
Environment
Environmental Chemistry
Environmental Health
Environmental science
Hydroxyapatite
Ions
Kinetics
Polymerization
Polymers
Radioactive Waste
Radioactive wastes
Radioisotopes
Research Article
Sorption
sorption isotherms
Strontium
Strontium - analysis
Strontium - chemistry
Thermodynamics
Waste Water Technology
Water Management
Water Pollution Control
title Evaluation of hydroxyapatite/poly(acrylamide-acrylic acid) for sorptive removal of strontium ions from aqueous solution
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