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Evaluation of hydroxyapatite/poly(acrylamide-acrylic acid) for sorptive removal of strontium ions from aqueous solution
A composite polymer, hydroxyapatite/poly(acrylamide-acrylic acid), was synthesized by gamma-induced polymerization. The factors affecting the sorption process were evaluated. The removal increased with time and achieved equilibrium after 1 h for all initial concentration ranges (10–50 mg/L). The hig...
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Published in: | Environmental science and pollution research international 2019-09, Vol.26 (25), p.25641-25655 |
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description | A composite polymer, hydroxyapatite/poly(acrylamide-acrylic acid), was synthesized by gamma-induced polymerization. The factors affecting the sorption process were evaluated. The removal increased with time and achieved equilibrium after 1 h for all initial concentration ranges (10–50 mg/L). The highest removal of Sr(II) was achieved using 50 mg/L at pH 6. The sorption process was found to follow a pseudo-first-order mechanism. The equilibrium data are best described by the Langmuir model, with a monolayer capacity of 53.59 mg/g. The values of thermodynamic parameters indicate that the sorption process is endothermic (
ΔH
> 0), increases randomness (
ΔS
> 0) and is spontaneous (
ΔG
< 0). The results imply that the composite could be used as a promising low-cost material for the removal of radionuclides from radioactive waste. |
doi_str_mv | 10.1007/s11356-019-05755-1 |
format | article |
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ΔH
> 0), increases randomness (
ΔS
> 0) and is spontaneous (
ΔG
< 0). The results imply that the composite could be used as a promising low-cost material for the removal of radionuclides from radioactive waste.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-019-05755-1</identifier><identifier>PMID: 31267395</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Acrylamide ; Acrylamide - chemistry ; Acrylates - chemistry ; Acrylic acid ; Acrylic Resins - chemistry ; Acrylics ; Aquatic Pollution ; Aqueous solutions ; Atmospheric Protection/Air Quality Control/Air Pollution ; Composite materials ; composite polymers ; Durapatite - chemistry ; Earth and Environmental Science ; Ecotoxicology ; Endothermic reactions ; endothermy ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental science ; Hydroxyapatite ; Ions ; Kinetics ; Polymerization ; Polymers ; Radioactive Waste ; Radioactive wastes ; Radioisotopes ; Research Article ; Sorption ; sorption isotherms ; Strontium ; Strontium - analysis ; Strontium - chemistry ; Thermodynamics ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Environmental science and pollution research international, 2019-09, Vol.26 (25), p.25641-25655</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2019</rights><rights>Environmental Science and Pollution Research is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c445t-72f622f750141273fd2bf9a24fa15b350ca7a1e04cfc6d73836f73e711008ea23</citedby><cites>FETCH-LOGICAL-c445t-72f622f750141273fd2bf9a24fa15b350ca7a1e04cfc6d73836f73e711008ea23</cites><orcidid>0000-0003-1264-675X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2250836779/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2250836779?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,11686,27922,27923,36058,36059,44361,74665</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31267395$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hassan, Hisham Soliman</creatorcontrib><creatorcontrib>El-Kamash, Ahmed Mohamed</creatorcontrib><creatorcontrib>Ibrahim, Haneen Abdel-Salam</creatorcontrib><title>Evaluation of hydroxyapatite/poly(acrylamide-acrylic acid) for sorptive removal of strontium ions from aqueous solution</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>A composite polymer, hydroxyapatite/poly(acrylamide-acrylic acid), was synthesized by gamma-induced polymerization. The factors affecting the sorption process were evaluated. The removal increased with time and achieved equilibrium after 1 h for all initial concentration ranges (10–50 mg/L). The highest removal of Sr(II) was achieved using 50 mg/L at pH 6. The sorption process was found to follow a pseudo-first-order mechanism. The equilibrium data are best described by the Langmuir model, with a monolayer capacity of 53.59 mg/g. The values of thermodynamic parameters indicate that the sorption process is endothermic (
ΔH
> 0), increases randomness (
ΔS
> 0) and is spontaneous (
ΔG
< 0). The results imply that the composite could be used as a promising low-cost material for the removal of radionuclides from radioactive waste.</description><subject>Acrylamide</subject><subject>Acrylamide - chemistry</subject><subject>Acrylates - chemistry</subject><subject>Acrylic acid</subject><subject>Acrylic Resins - chemistry</subject><subject>Acrylics</subject><subject>Aquatic Pollution</subject><subject>Aqueous solutions</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Composite materials</subject><subject>composite polymers</subject><subject>Durapatite - chemistry</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Endothermic reactions</subject><subject>endothermy</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental science</subject><subject>Hydroxyapatite</subject><subject>Ions</subject><subject>Kinetics</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Radioactive Waste</subject><subject>Radioactive wastes</subject><subject>Radioisotopes</subject><subject>Research Article</subject><subject>Sorption</subject><subject>sorption isotherms</subject><subject>Strontium</subject><subject>Strontium - analysis</subject><subject>Strontium - chemistry</subject><subject>Thermodynamics</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>M0C</sourceid><recordid>eNqFkU1PFTEUhhujkQv6B1yQJm5gUenp5-2SEAQSEje6bno7rQ6ZmQ7tDDr_3g4XJWGhqzbtc55z2hehD0A_AaX6rABwqQgFQ6jUUhJ4hTagQBAtjHmNNtQIQYALcYAOS7mjlFHD9Ft0wIEpzY3coJ-XD66b3dSmAaeIfyxNTr8WN9aTKZyNqVtOnM9L5_q2CeRx23rsfNuc4pgyLimPU_sQcA59qqpVUqachqmde1ytBceceuzu55DmUvluXpu9Q2-i60p4_7QeoW-fL79eXJPbL1c3F-e3xAshJ6JZVIxFLSkIYJrHhu2icUxEB3LHJfVOOwhU-OhVo_mWq6h50FA_aBsc40foZO8dc6ojlMn2bfGh69ywzmMZB8m2ihr1f5RJUFvDqazoxxfoXZrzUB-yUrROobWpFNtTPqdScoh2zG3v8mKB2jVBu0_Q1gTtY4IWatHxk3re9aH5W_InsgrwPVDq1fA95Ofe_9D-Bur2p5k</recordid><startdate>20190901</startdate><enddate>20190901</enddate><creator>Hassan, Hisham Soliman</creator><creator>El-Kamash, Ahmed Mohamed</creator><creator>Ibrahim, Haneen Abdel-Salam</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>7WY</scope><scope>7WZ</scope><scope>7X7</scope><scope>7XB</scope><scope>87Z</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8FL</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FRNLG</scope><scope>FYUFA</scope><scope>F~G</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K60</scope><scope>K6~</scope><scope>K9.</scope><scope>L.-</scope><scope>M0C</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7N</scope><scope>P64</scope><scope>PATMY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0003-1264-675X</orcidid></search><sort><creationdate>20190901</creationdate><title>Evaluation of hydroxyapatite/poly(acrylamide-acrylic acid) for sorptive removal of strontium ions from aqueous solution</title><author>Hassan, Hisham Soliman ; El-Kamash, Ahmed Mohamed ; Ibrahim, Haneen Abdel-Salam</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c445t-72f622f750141273fd2bf9a24fa15b350ca7a1e04cfc6d73836f73e711008ea23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acrylamide</topic><topic>Acrylamide - 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Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hassan, Hisham Soliman</au><au>El-Kamash, Ahmed Mohamed</au><au>Ibrahim, Haneen Abdel-Salam</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Evaluation of hydroxyapatite/poly(acrylamide-acrylic acid) for sorptive removal of strontium ions from aqueous solution</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2019-09-01</date><risdate>2019</risdate><volume>26</volume><issue>25</issue><spage>25641</spage><epage>25655</epage><pages>25641-25655</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>A composite polymer, hydroxyapatite/poly(acrylamide-acrylic acid), was synthesized by gamma-induced polymerization. The factors affecting the sorption process were evaluated. The removal increased with time and achieved equilibrium after 1 h for all initial concentration ranges (10–50 mg/L). The highest removal of Sr(II) was achieved using 50 mg/L at pH 6. The sorption process was found to follow a pseudo-first-order mechanism. The equilibrium data are best described by the Langmuir model, with a monolayer capacity of 53.59 mg/g. The values of thermodynamic parameters indicate that the sorption process is endothermic (
ΔH
> 0), increases randomness (
ΔS
> 0) and is spontaneous (
ΔG
< 0). The results imply that the composite could be used as a promising low-cost material for the removal of radionuclides from radioactive waste.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>31267395</pmid><doi>10.1007/s11356-019-05755-1</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0003-1264-675X</orcidid></addata></record> |
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subjects | Acrylamide Acrylamide - chemistry Acrylates - chemistry Acrylic acid Acrylic Resins - chemistry Acrylics Aquatic Pollution Aqueous solutions Atmospheric Protection/Air Quality Control/Air Pollution Composite materials composite polymers Durapatite - chemistry Earth and Environmental Science Ecotoxicology Endothermic reactions endothermy Environment Environmental Chemistry Environmental Health Environmental science Hydroxyapatite Ions Kinetics Polymerization Polymers Radioactive Waste Radioactive wastes Radioisotopes Research Article Sorption sorption isotherms Strontium Strontium - analysis Strontium - chemistry Thermodynamics Waste Water Technology Water Management Water Pollution Control |
title | Evaluation of hydroxyapatite/poly(acrylamide-acrylic acid) for sorptive removal of strontium ions from aqueous solution |
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