Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds: the distinct distance tuning of C-C and its antipodal B-B

Four-fold aryl substituted o-carborane derivatives with defined patterns of substitution at the antipodal region of the cluster carbon atoms have been achieved. It is proven that this region is congested but lacks steric hindrance. Also, the two antipodal sites C -C and B9-B12 are affected very dist...

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Published in:Chemical communications (Cambridge, England) England), 2019-08, Vol.55 (61), p.8927-8930
Main Authors: Kelemen, Zsolt, Pepiol, Ariadna, Lupu, Marius, Sillanpää, Reijo, Hänninen, Mikko M, Teixidor, Francesc, Viñas, Clara
Format: Article
Language:English
Subjects:
Aromatic compounds
Carborane
Crystallography
Icosahedral phase
Steric hindrance
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description Four-fold aryl substituted o-carborane derivatives with defined patterns of substitution at the antipodal region of the cluster carbon atoms have been achieved. It is proven that this region is congested but lacks steric hindrance. Also, the two antipodal sites C -C and B9-B12 are affected very distinctly by electron donor substituents.
doi_str_mv 10.1039/c9cc04526k
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source Royal Society of Chemistry
subjects Aromatic compounds
Carborane
Crystallography
Icosahedral phase
Steric hindrance
title Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds: the distinct distance tuning of C-C and its antipodal B-B
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