Ligand-directed assembly engineering of trapezoidal {Ti} building blocks stabilized by dimethylglyoxime

Through ligand-directed assembly of trapezoidal {Ti 5 } building blocks stabilized by dimethylglyoxime, eight titanium-oxo molecular clusters with a sandwich or square planar type structures were successfully constructed, including the first success on the combination of porphyrin and titanium-oxo c...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2019-07, Vol.48 (27), p.9916-9919
Main Authors: Ding, Qing-Rong, Xu, Gui-Lan, Zhang, Lei, Zhang, Jian
Format: Article
Language:English
Subjects:
Assembly
Crystallography
Ligands
Molecular clusters
Titanium
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Summary:Through ligand-directed assembly of trapezoidal {Ti 5 } building blocks stabilized by dimethylglyoxime, eight titanium-oxo molecular clusters with a sandwich or square planar type structures were successfully constructed, including the first success on the combination of porphyrin and titanium-oxo clusters. A facile approach of ligand-directed assembly of trapezoidal {Ti 5 } building blocks was successfully established, which gave rise to interesting hybrid clusters including the first molecular assembly of porphyrin photosensitizer and titanium-oxo cluster.
ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt02032b