Facile synthesis of a micro-scale MOF host-guest with long-lasting phosphorescence and enhanced optoelectronic performance

Micro-scale MOFs with a persistent phosphorescence lifetime of 900 ms can be facilely synthesized by a fast precipitation process in aqueous solution. The in situ encapsulation of a dye into the MOF matrix can expressly tune the phosphorescence color from green to a rare example of red emission with...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2019-09, Vol.55 (74), p.11099-11102
Main Authors: Yang, Xiao-Gang, Lu, Xiao-Min, Zhai, Zhi-Min, Zhao, Ying, Liu, Xin-Yi, Ma, Lu-Fang, Zang, Shuang-Quan
Format: Article
Language:English
Subjects:
Aqueous solutions
Chemical precipitation
Crystallography
Optoelectronics
Phosphorescence
Water splitting
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Summary:Micro-scale MOFs with a persistent phosphorescence lifetime of 900 ms can be facilely synthesized by a fast precipitation process in aqueous solution. The in situ encapsulation of a dye into the MOF matrix can expressly tune the phosphorescence color from green to a rare example of red emission with a lifetime of 450 ms, highly enhancing the photoelectrocatalytic water splitting.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc05708k