Vapor‐Phase Linker Exchange of the Metal–Organic Framework ZIF‐8: A Solvent‐Free Approach to Post‐synthetic Modification

Zeolitic imidazolate frameworks (ZIFs) are a sub‐class of metal–organic frameworks (MOFs). Although generally stable, ZIFs can undergo post‐synthetic linker exchange (PSLE) in solution under mild conditions. Herein, we present a novel, solvent‐free approach to post‐synthetic linker exchange through...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2019-12, Vol.58 (51), p.18471-18475
Main Authors: Marreiros, João, Van Dommelen, Lenz, Fleury, Guillaume, Oliveira‐Silva, Rodrigo, Stassin, Timothée, Iacomi, Paul, Furukawa, Shuhei, Sakellariou, Dimitrios, Llewellyn, Philip L., Roeffaers, Maarten, Ameloot, Rob
Format: Article
Language:English
Subjects:
Exchanging
Metal-organic frameworks
Metals
mixed-linker ZIFs
solvent-free modification
Solvents
vapor-phase linker exchange
Vapors
Zeolites
ZIF-8
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Summary:Zeolitic imidazolate frameworks (ZIFs) are a sub‐class of metal–organic frameworks (MOFs). Although generally stable, ZIFs can undergo post‐synthetic linker exchange (PSLE) in solution under mild conditions. Herein, we present a novel, solvent‐free approach to post‐synthetic linker exchange through exposure to linker vapor. Vaporous materials: Although generally stable, zeolitic imidazolate frameworks (ZIFs) can undergo post‐synthetic linker exchange (PSLE) in solution under mild conditions. A novel, solvent‐free approach to PSLE through exposure to linker vapor is presented.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201912088