A flower-like hybrid material composed of Fe3O4, graphene oxide and CdSe nanodots for magnetic solid phase extraction of ibuprofen prior to its quantification by HPLC detection

A flower-like Fe 3 O 4 /GO/CdSe nanodot magnetic hybrid material was produced and applied to magnetic solid-phase extraction of ibuprofen from pharmaceuticals, water, and urine samples. The material was characterized by X-ray diffraction, Raman spectroscopy and field emission scanning electron micro...

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Bibliographic Details
Published in:Mikrochimica acta (1966) 2019-11, Vol.186 (11), p.744-744, Article 744
Main Authors: Sarp, Gokhan, Yilmaz, Erkan
Format: Article
Language:English
Subjects:
Acetone
Analytical Chemistry
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Elution
Field emission microscopy
Field emission spectroscopy
Graphene
Ibuprofen
Iron oxides
Microengineering
Nanochemistry
Nanotechnology
Nonsteroidal anti-inflammatory drugs
Original Paper
Raman spectroscopy
Solid phases
Sorbents
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Summary:A flower-like Fe 3 O 4 /GO/CdSe nanodot magnetic hybrid material was produced and applied to magnetic solid-phase extraction of ibuprofen from pharmaceuticals, water, and urine samples. The material was characterized by X-ray diffraction, Raman spectroscopy and field emission scanning electron microscopy and SEM-EDX. The pH value, volume of sample solution, amount of sorbent, type and volume of elution solvent and extraction time were optimized. Following elution with acetone, ibuprofen was quantified by HPLC-DAD detection. The recoveries of ibuprofen from spiked real samples ranged between 87 and 109%, and the intra-day and inter-day relative standard deviations from 1.25 to 3.02%. The limit of detection, limit of quantification and preconcentration factor are 0.36 ng·mL −1 ,1.20 ng·mL −1 and 150, respectively. Graphical abstract Schematic representation of the combination of flower-like Fe 3 O 4 /GO/CdSe nanodot-based magnetic solid phase extraction (MSPE) and high-performance liquid chromatography (HPLC) procedure for the extraction and analysis of ibuprofen in pharmaceuticals, water, and urine samples.
ISSN:0026-3672
1436-5073
DOI:10.1007/s00604-019-3875-x