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A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water
The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO.
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Published in: | Chemical communications (Cambridge, England) England), 2019, Vol.55 (98), p.14781-14784 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
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Summary: | The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c9cc08094e |