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A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2019, Vol.55 (98), p.14781-14784
Main Authors: Huang, Ning-Yu, Zhang, Xue-Wen, Xu, Yu-Zhi, Liao, Pei-Qin, Chen, Xiao-Ming
Format: Article
Language:English
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Description
Summary:The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc08094e