A new type of composite MOFs based on high-valent Sb()-based units and cuprous-halide clusters

An unusual high-valent Sb( v )-based unit [SbL 2 ] − (L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol) was developed for the first time to combine with various cuprous-halide clusters for the construction of a brand-new class of heterometallic MOFs. This work not only promotes the limited dev...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2019-12, Vol.55 (1), p.15113-15116
Main Authors: Lin, Li-Dan, Li, Zhong, Liu, Jin-Hua, Sun, Yan-Qiong, Li, Xin-Xiong, Zheng, Shou-Tian
Format: Article
Language:English
Subjects:
Clusters
Composite materials
Crystallography
Metal-organic frameworks
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Summary:An unusual high-valent Sb( v )-based unit [SbL 2 ] − (L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol) was developed for the first time to combine with various cuprous-halide clusters for the construction of a brand-new class of heterometallic MOFs. This work not only promotes the limited development of Sb-based MOFs, but also provides a practical strategy for developing new types of composite materials. In this work, an unusual high-valent Sb( v )-based [SbL 2 ] − unit was developed for the first time to combine with various cuprous-halide clusters for the construction of a brand-new class of heterometallic MOFs.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc08443f