Various Cd(ii) coordination polymers induced by carboxylates: multi-functional detection of Fe3+, anions, aspartic acids and bovine serum albumin

By adjusting carboxylates, six Cd(ii) coordination polymers based on a naphthalene–methylene mixed-bridged-amide ligand, [Cd(L)(DNBA)2] (1), [Cd2(L)2(BDC)2(H2O)2]·2H2O (2), [Cd(L)(1,4-CHDA)] (3), [Cd(L)(HIPA)(H2O)]·H2O (4), [Cd(L)(MIP)]·H2O (5), and [Cd(L)(PMA)0.5(H2O)]·H2O (6) [L = N,N′-bis(4-methy...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2020-01, Vol.49 (3), p.737-749
Main Authors: Liu, Guocheng, Li, Yan, Chi, Jie, Xu, Na, Wang, Xiuli, Lin, Hongyan, Chen, Baokuan, Li, Jianrong
Format: Article
Language:English
Subjects:
Acids
Anions
Aspartic acid
Cadmium
Carboxylates
Coordination polymers
Crystallography
Fluorescence
Functional groups
Naphthalene
Query languages
Selectivity
Serum albumin
Topology
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Liu, Guocheng
Li, Yan
Chi, Jie
Xu, Na
Wang, Xiuli
Lin, Hongyan
Chen, Baokuan
Li, Jianrong
description By adjusting carboxylates, six Cd(ii) coordination polymers based on a naphthalene–methylene mixed-bridged-amide ligand, [Cd(L)(DNBA)2] (1), [Cd2(L)2(BDC)2(H2O)2]·2H2O (2), [Cd(L)(1,4-CHDA)] (3), [Cd(L)(HIPA)(H2O)]·H2O (4), [Cd(L)(MIP)]·H2O (5), and [Cd(L)(PMA)0.5(H2O)]·H2O (6) [L = N,N′-bis(4-methylenepyridin-4-yl)-1,4-naphthalene dicarboxamide, HDNBA = 3,5-dinitrobenzoic acid, H2BDC = 1,4-benzenedicarboxylic acid, 1,4-H2CHDA = 1,4-cyclohexanedicarboxylic acid, H2HIPA = 5-hydroxyisophthalic acid, H2MIP = 5-methylisophthalic acid and H4PMA = pyromellitic acid] have been synthesized under hydrothermal conditions. 1 shows a 4-c sql coplanar structure. 2 exhibits a 2-fold vertical interpenetrating structure based on wave-like 4-c sql layers. 3 shows a (3,5)-c pnh network containing a unique μ3-L. 4 features a 4-c sql wave-like network. 5 and 6 exhibit 3D structures with 6-c pcu and 4-c mog topologies. The number of carboxyl groups and functional group positions of the carboxylates have an important influence on the structures of the title complexes. The fluorescent responses of 1–6 towards Fe3+, anions, aspartic acid and bovine serum albumin were investigated. Among them, 4 shows sensitivity and selectivity (KSV = 1.16 × 104 L mol−1 for Fe3+, 1.03 × 104 L mol−1 for CrO42−, 1.08 × 104 L mol−1 for Cr2O72−, 1.17 × 104 L mol−1 for MnO4− and 1.05 × 104 L mol−1 for aspartic acid).
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The number of carboxyl groups and functional group positions of the carboxylates have an important influence on the structures of the title complexes. The fluorescent responses of 1–6 towards Fe3+, anions, aspartic acid and bovine serum albumin were investigated. Among them, 4 shows sensitivity and selectivity (KSV = 1.16 × 104 L mol−1 for Fe3+, 1.03 × 104 L mol−1 for CrO42−, 1.08 × 104 L mol−1 for Cr2O72−, 1.17 × 104 L mol−1 for MnO4− and 1.05 × 104 L mol−1 for aspartic acid).</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c9dt04103f</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Acids ; Anions ; Aspartic acid ; Cadmium ; Carboxylates ; Coordination polymers ; Crystallography ; Fluorescence ; Functional groups ; Naphthalene ; Query languages ; Selectivity ; Serum albumin ; Topology</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2020-01, Vol.49 (3), p.737-749</ispartof><rights>Copyright Royal Society of Chemistry 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Liu, Guocheng</creatorcontrib><creatorcontrib>Li, Yan</creatorcontrib><creatorcontrib>Chi, Jie</creatorcontrib><creatorcontrib>Xu, Na</creatorcontrib><creatorcontrib>Wang, Xiuli</creatorcontrib><creatorcontrib>Lin, Hongyan</creatorcontrib><creatorcontrib>Chen, Baokuan</creatorcontrib><creatorcontrib>Li, Jianrong</creatorcontrib><title>Various Cd(ii) coordination polymers induced by carboxylates: multi-functional detection of Fe3+, anions, aspartic acids and bovine serum albumin</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>By adjusting carboxylates, six Cd(ii) coordination polymers based on a naphthalene–methylene mixed-bridged-amide ligand, [Cd(L)(DNBA)2] (1), [Cd2(L)2(BDC)2(H2O)2]·2H2O (2), [Cd(L)(1,4-CHDA)] (3), [Cd(L)(HIPA)(H2O)]·H2O (4), [Cd(L)(MIP)]·H2O (5), and [Cd(L)(PMA)0.5(H2O)]·H2O (6) [L = N,N′-bis(4-methylenepyridin-4-yl)-1,4-naphthalene dicarboxamide, HDNBA = 3,5-dinitrobenzoic acid, H2BDC = 1,4-benzenedicarboxylic acid, 1,4-H2CHDA = 1,4-cyclohexanedicarboxylic acid, H2HIPA = 5-hydroxyisophthalic acid, H2MIP = 5-methylisophthalic acid and H4PMA = pyromellitic acid] have been synthesized under hydrothermal conditions. 1 shows a 4-c sql coplanar structure. 2 exhibits a 2-fold vertical interpenetrating structure based on wave-like 4-c sql layers. 3 shows a (3,5)-c pnh network containing a unique μ3-L. 4 features a 4-c sql wave-like network. 5 and 6 exhibit 3D structures with 6-c pcu and 4-c mog topologies. The number of carboxyl groups and functional group positions of the carboxylates have an important influence on the structures of the title complexes. The fluorescent responses of 1–6 towards Fe3+, anions, aspartic acid and bovine serum albumin were investigated. Among them, 4 shows sensitivity and selectivity (KSV = 1.16 × 104 L mol−1 for Fe3+, 1.03 × 104 L mol−1 for CrO42−, 1.08 × 104 L mol−1 for Cr2O72−, 1.17 × 104 L mol−1 for MnO4− and 1.05 × 104 L mol−1 for aspartic acid).</description><subject>Acids</subject><subject>Anions</subject><subject>Aspartic acid</subject><subject>Cadmium</subject><subject>Carboxylates</subject><subject>Coordination polymers</subject><subject>Crystallography</subject><subject>Fluorescence</subject><subject>Functional groups</subject><subject>Naphthalene</subject><subject>Query languages</subject><subject>Selectivity</subject><subject>Serum albumin</subject><subject>Topology</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNpdkE9LxDAQxYsouK5e_AQBLytazb92G2-yuCoseFGvyzSZQpa0qU0j7sfwG5tV8eDp_ebx5sFMlp0yesWoUNdamZHKhM1eNmFyPs8VF3L_j3l5mB2FsKGUc1rwSfb5CoP1MZCFmVl7TrT3g7EdjNZ3pPdu2-IQiO1M1GhIvSUahtp_bB2MGG5IG91o8yZ2ercAjhgc8ZuJb8gSxcUlgS6NIWnoYRitJqCtCclOff7ddkgCDrEl4OrY2u44O2jABTz51Wn2srx7Xjzkq6f7x8XtKu-ZLMe8rJRktZECGFWsqkQxbyooBUOkyEtgBpSiGhqK2qBOljDUVKYWJcWaMTHNZj-9_eDfIoZx3dqg0TnoMD1kzQWvhJxXhUrRs3_RjY9DOneXklxyVgghvgDCG3Z9</recordid><startdate>20200121</startdate><enddate>20200121</enddate><creator>Liu, Guocheng</creator><creator>Li, Yan</creator><creator>Chi, Jie</creator><creator>Xu, Na</creator><creator>Wang, Xiuli</creator><creator>Lin, Hongyan</creator><creator>Chen, Baokuan</creator><creator>Li, Jianrong</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20200121</creationdate><title>Various Cd(ii) coordination polymers induced by carboxylates: multi-functional detection of Fe3+, anions, aspartic acids and bovine serum albumin</title><author>Liu, Guocheng ; 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The number of carboxyl groups and functional group positions of the carboxylates have an important influence on the structures of the title complexes. The fluorescent responses of 1–6 towards Fe3+, anions, aspartic acid and bovine serum albumin were investigated. Among them, 4 shows sensitivity and selectivity (KSV = 1.16 × 104 L mol−1 for Fe3+, 1.03 × 104 L mol−1 for CrO42−, 1.08 × 104 L mol−1 for Cr2O72−, 1.17 × 104 L mol−1 for MnO4− and 1.05 × 104 L mol−1 for aspartic acid).</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c9dt04103f</doi><tpages>13</tpages></addata></record>
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subjects Acids
Anions
Aspartic acid
Cadmium
Carboxylates
Coordination polymers
Crystallography
Fluorescence
Functional groups
Naphthalene
Query languages
Selectivity
Serum albumin
Topology
title Various Cd(ii) coordination polymers induced by carboxylates: multi-functional detection of Fe3+, anions, aspartic acids and bovine serum albumin
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