Kinetics of oxygen reduction at oxide-derived Pd electrodes in alkaline solution

Oxygen reduction at oxide-derived Pd electrodes is investigated by using the rotating disc electrode technique. On the basis of these experiments along with further data analysis (ie reaction orders, Tafel slopes, etc.), a mechanism of oxygen reduction on an oxide-derived Pd electrode is proposed to...

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Bibliographic Details
Published in:Electrochimica acta 1997, Vol.42 (4), p.557-565
Main Authors: Chang, Chia-Chin, Wen, Ten-Chin, Tien, Hsien-Ju
Format: Article
Language:English
Subjects:
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
oxide-derived Pd electrode
oxygen reduction
Rotating disc electrode
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Summary:Oxygen reduction at oxide-derived Pd electrodes is investigated by using the rotating disc electrode technique. On the basis of these experiments along with further data analysis (ie reaction orders, Tafel slopes, etc.), a mechanism of oxygen reduction on an oxide-derived Pd electrode is proposed to explain the observed rate equation.
ISSN:0013-4686
1873-3859
DOI:10.1016/S0013-4686(96)00195-8