Chemical-Shift Effects and Origin of the Pd 3d Core-Level Satellite in CuPd Alloys

The palladium 3d sub(3) sub(/) sub(2) sub(,) sub(5) sub(/) sub(2) core level satellites and valence-band satellite are studied experimentally. The nature of the formercan be elucidated by a comparison with the rhodium 3d specturm. A substantial chemical shift is observed for the core-level satellite...

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Bibliographic Details
Published in:Physical review letters 1980-01, Vol.45 (9), p.754-757
Main Authors: Nartensson, N, Nyholm, R, Johansson, B
Format: Article
Language:English
Online Access:Get full text
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Summary:The palladium 3d sub(3) sub(/) sub(2) sub(,) sub(5) sub(/) sub(2) core level satellites and valence-band satellite are studied experimentally. The nature of the formercan be elucidated by a comparison with the rhodium 3d specturm. A substantial chemical shift is observed for the core-level satellites in Cu-Pd alloys. The final state in the Auger process M sub(5)VV is found to be quasiatomic and is identified with the valence-band satellite.
ISSN:0031-9007
DOI:10.1103/PhysRevLett.45.754