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Chemical-Shift Effects and Origin of the Pd 3d Core-Level Satellite in CuPd Alloys

The palladium 3d sub(3) sub(/) sub(2) sub(,) sub(5) sub(/) sub(2) core level satellites and valence-band satellite are studied experimentally. The nature of the formercan be elucidated by a comparison with the rhodium 3d specturm. A substantial chemical shift is observed for the core-level satellite...

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Published in:Physical review letters 1980-01, Vol.45 (9), p.754-757
Main Authors: Nartensson, N, Nyholm, R, Johansson, B
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Language:English
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creator Nartensson, N
Nyholm, R
Johansson, B
description The palladium 3d sub(3) sub(/) sub(2) sub(,) sub(5) sub(/) sub(2) core level satellites and valence-band satellite are studied experimentally. The nature of the formercan be elucidated by a comparison with the rhodium 3d specturm. A substantial chemical shift is observed for the core-level satellites in Cu-Pd alloys. The final state in the Auger process M sub(5)VV is found to be quasiatomic and is identified with the valence-band satellite.
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title Chemical-Shift Effects and Origin of the Pd 3d Core-Level Satellite in CuPd Alloys
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