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Sodium-hydrogen interdiffusion in sodium silicate glasses
The hydration of Na 2O · 3 SiO 2 glasses is studied using the sputter-induced photon spectrometry technique (SIPS) to measure the depth-profiles of hydrogen and sodium. The results clearly show a penetration of hydrogen and a leaching of sodium in the glass. The thicknesses of the hydrated layers ar...
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Published in: | Journal of non-crystalline solids 1980, Vol.41 (1), p.89-98 |
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Language: | English |
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cites | cdi_FETCH-LOGICAL-c250t-8967cc7038e827850d71fa154ef57dd2e1d47483038ef0a465a138668b967b8f3 |
container_end_page | 98 |
container_issue | 1 |
container_start_page | 89 |
container_title | Journal of non-crystalline solids |
container_volume | 41 |
creator | Houser, C.A. Herman, J.S. Tsong, I.S.T. White, W.B. Lanford, W.A. |
description | The hydration of Na
2O · 3 SiO
2 glasses is studied using the sputter-induced photon spectrometry technique (SIPS) to measure the depth-profiles of hydrogen and sodium. The results clearly show a penetration of hydrogen and a leaching of sodium in the glass. The thicknesses of the hydrated layers are determined as functions of time and temperature. The thicknes dependence on the square root of time indicates that a diffusion process is in operation. The data are fitted to he Doremus model of interdiffusing ions and the diffusion coefficients for hydrogen and sodium are calculated. |
doi_str_mv | 10.1016/0022-3093(80)90194-5 |
format | article |
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2O · 3 SiO
2 glasses is studied using the sputter-induced photon spectrometry technique (SIPS) to measure the depth-profiles of hydrogen and sodium. The results clearly show a penetration of hydrogen and a leaching of sodium in the glass. The thicknesses of the hydrated layers are determined as functions of time and temperature. The thicknes dependence on the square root of time indicates that a diffusion process is in operation. The data are fitted to he Doremus model of interdiffusing ions and the diffusion coefficients for hydrogen and sodium are calculated.</description><identifier>ISSN: 0022-3093</identifier><identifier>EISSN: 1873-4812</identifier><identifier>DOI: 10.1016/0022-3093(80)90194-5</identifier><language>eng</language><publisher>Elsevier B.V</publisher><ispartof>Journal of non-crystalline solids, 1980, Vol.41 (1), p.89-98</ispartof><rights>1980</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c250t-8967cc7038e827850d71fa154ef57dd2e1d47483038ef0a465a138668b967b8f3</citedby><cites>FETCH-LOGICAL-c250t-8967cc7038e827850d71fa154ef57dd2e1d47483038ef0a465a138668b967b8f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/0022309380901945$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3555,4024,27923,27924,27925,46004</link.rule.ids></links><search><creatorcontrib>Houser, C.A.</creatorcontrib><creatorcontrib>Herman, J.S.</creatorcontrib><creatorcontrib>Tsong, I.S.T.</creatorcontrib><creatorcontrib>White, W.B.</creatorcontrib><creatorcontrib>Lanford, W.A.</creatorcontrib><title>Sodium-hydrogen interdiffusion in sodium silicate glasses</title><title>Journal of non-crystalline solids</title><description>The hydration of Na
2O · 3 SiO
2 glasses is studied using the sputter-induced photon spectrometry technique (SIPS) to measure the depth-profiles of hydrogen and sodium. The results clearly show a penetration of hydrogen and a leaching of sodium in the glass. The thicknesses of the hydrated layers are determined as functions of time and temperature. The thicknes dependence on the square root of time indicates that a diffusion process is in operation. The data are fitted to he Doremus model of interdiffusing ions and the diffusion coefficients for hydrogen and sodium are calculated.</description><issn>0022-3093</issn><issn>1873-4812</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1980</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMoWFf_gYeeRA_VpEma9CLI4hcseFDPIZtM1ki3XTOtsP_edlc8Opdh4HlfmIeQc0avGWXVDaVlWXBa80tNr2rKalHIA5IxrXghNCsPSfaHHJMTxE86juI6I_Vr5-OwLj62PnUraPPY9pB8DGHA2E1njjsix9hEZ3vIV41FBDwlR8E2CGe_e0beH-7f5k_F4uXxeX63KFwpaV_oulLOKco16FJpSb1iwTIpIEjlfQnMCyU0n4BAraikZVxXlV6OwaUOfEYu9r2b1H0NgL1ZR3TQNLaFbkBTTnQtxQiKPehSh5ggmE2Ka5u2hlEzeTKTBDNJMJqanScjx9jtPgbjE98RkkEXoXXgYwLXG9_F_wt-AL1AbiI</recordid><startdate>1980</startdate><enddate>1980</enddate><creator>Houser, C.A.</creator><creator>Herman, J.S.</creator><creator>Tsong, I.S.T.</creator><creator>White, W.B.</creator><creator>Lanford, W.A.</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>1980</creationdate><title>Sodium-hydrogen interdiffusion in sodium silicate glasses</title><author>Houser, C.A. ; Herman, J.S. ; Tsong, I.S.T. ; White, W.B. ; Lanford, W.A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c250t-8967cc7038e827850d71fa154ef57dd2e1d47483038ef0a465a138668b967b8f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1980</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Houser, C.A.</creatorcontrib><creatorcontrib>Herman, J.S.</creatorcontrib><creatorcontrib>Tsong, I.S.T.</creatorcontrib><creatorcontrib>White, W.B.</creatorcontrib><creatorcontrib>Lanford, W.A.</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of non-crystalline solids</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Houser, C.A.</au><au>Herman, J.S.</au><au>Tsong, I.S.T.</au><au>White, W.B.</au><au>Lanford, W.A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sodium-hydrogen interdiffusion in sodium silicate glasses</atitle><jtitle>Journal of non-crystalline solids</jtitle><date>1980</date><risdate>1980</risdate><volume>41</volume><issue>1</issue><spage>89</spage><epage>98</epage><pages>89-98</pages><issn>0022-3093</issn><eissn>1873-4812</eissn><abstract>The hydration of Na
2O · 3 SiO
2 glasses is studied using the sputter-induced photon spectrometry technique (SIPS) to measure the depth-profiles of hydrogen and sodium. The results clearly show a penetration of hydrogen and a leaching of sodium in the glass. The thicknesses of the hydrated layers are determined as functions of time and temperature. The thicknes dependence on the square root of time indicates that a diffusion process is in operation. The data are fitted to he Doremus model of interdiffusing ions and the diffusion coefficients for hydrogen and sodium are calculated.</abstract><pub>Elsevier B.V</pub><doi>10.1016/0022-3093(80)90194-5</doi><tpages>10</tpages></addata></record> |
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title | Sodium-hydrogen interdiffusion in sodium silicate glasses |
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