Double-layered honeycomb architectures constructed via hierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles

A hexagonal cobalt(ii) metallacycle and its "lipid packaged" derivatives, [Co (R-bisterpy) ]X (R = H, OC H , OC H ; X = BF , C -Glu), have been synthesized and characterized. The compounds incorporating BF anions formed sphere-like aggregates while the compounds with C -Glu lipid anions ga...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-05, Vol.56 (43), p.5835-5838
Main Authors: Akiyoshi, Ryohei, Kuroiwa, Keita, Sakuragi, Mina, Yoshimoto, Soichiro, Ohtani, Ryo, Nakamura, Masaaki, Lindoy, Leonard F, Hayami, Shinya
Format: Article
Language:English
Subjects:
Anions
Cobalt
Crossovers
Electron density
Electron spin
Honeycomb construction
Lipids
Organometallic compounds
Self-assembly
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Summary:A hexagonal cobalt(ii) metallacycle and its "lipid packaged" derivatives, [Co (R-bisterpy) ]X (R = H, OC H , OC H ; X = BF , C -Glu), have been synthesized and characterized. The compounds incorporating BF anions formed sphere-like aggregates while the compounds with C -Glu lipid anions gave double-layered honeycomb architectures composed of hexagonal stacked tubular structures, which exhibit spin crossover behaviour.
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc02628j