Transport properties of ground state nitrogen atoms

In view of the dependence of the transport properties of dilute monatomic gases on the two-body, atom-atom interaction potential, any one of four potential energy curves corresponding to the N2 molecule can be followed when two ground state N atoms interact. Transport collision integrals for the 1Si...

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Published in:The Journal of chemical physics 1983-08, Vol.79 (3), p.1462-1468
Main Authors: Rainwater, J. C., Biolsi, L., Biolsi, K. J., Holland, P. M.
Format: Article
Language:English
Subjects:
Exact sciences and technology
Kinetic and transport theory of gases
Physics
Physics of gases
Physics of gases, plasmas and electric discharges
Thermodynamics And Statistical Physics
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description In view of the dependence of the transport properties of dilute monatomic gases on the two-body, atom-atom interaction potential, any one of four potential energy curves corresponding to the N2 molecule can be followed when two ground state N atoms interact. Transport collision integrals for the 1Sigma(+)g and 3Sigma(+)u states have been calculated by representing their potentials with the Hulburt-Hirschfelder (1941, 1961) potential. The 5Sigma(+)g state has a large local maximum requiring changes in a previously used computational procedure, and its potential has also been represented by a Hulburt-Hirschfelder potential. Collision integrals for the 7Sigma(+)u state have been obtained through the direct use of a recently proposed theoretical potential for this state. The collision integrals are compared with results gathered from previous studies.
doi_str_mv 10.1063/1.445909
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source American Institute of Physics (AIP) Publications
subjects Exact sciences and technology
Kinetic and transport theory of gases
Physics
Physics of gases
Physics of gases, plasmas and electric discharges
Thermodynamics And Statistical Physics
title Transport properties of ground state nitrogen atoms
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