On the kinetics of the cathodic deposition of aluminium on glassy carbon and tungsten electrodes from AlCl3+NaCl+KCl melts

The kinetics of Al deposition from AlCl3 + NaCl + KCl melts were studied using several electrochemical relaxation techniques at 975K. The deposition process was found to be controlled mainly by diffusion in the concentration range under study (cAlCl3 = 5 x 10 exp --5 --5 x 10 exp --4 mol cm exp --3...

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Published in:Journal of electroanalytical chemistry and interfacial electrochemistry 1986-10, Vol.210 (1), p.127-136
Main Authors: YONG JIAN ZHANG, BJØRGUM, A, ERIKSON, U, TUNOLD, R, ØDEGARD, R
Format: Article
Language:English
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Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
High temperature electrochemistry (including molten salts)
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description The kinetics of Al deposition from AlCl3 + NaCl + KCl melts were studied using several electrochemical relaxation techniques at 975K. The deposition process was found to be controlled mainly by diffusion in the concentration range under study (cAlCl3 = 5 x 10 exp --5 --5 x 10 exp --4 mol cm exp --3 ). The charge transfer reaction seems to be rather fast. No sign of a slow dissociation of a complex preceding the charge transfer was observed. Diffusion coefficients and rate constants have been obtained. 16 ref.--AA(US).
doi_str_mv 10.1016/0022-0728(86)90318-9
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subjects Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
High temperature electrochemistry (including molten salts)
title On the kinetics of the cathodic deposition of aluminium on glassy carbon and tungsten electrodes from AlCl3+NaCl+KCl melts
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