Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction

A flexible coordination polymer with a naphthalenediimide core exhibited reversible desorption-adsorption of solvent molecules and an enhancement of electrical conductivity (∼10 −7 S cm −1 ) upon chemical reduction using hydrazine. Postsynthetic chemical reduction enhanced the electrical conductivit...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-08, Vol.56 (61), p.8619-8622
Main Authors: Fuku, Kentaro, Miyata, Momoka, Takaishi, Shinya, Yoshida, Takefumi, Yamashita, Masahiro, Hoshino, Norihisa, Akutagawa, Tomoyuki, Ohtsu, Hiroyoshi, Kawano, Masaki, Iguchi, Hiroaki
Format: Article
Language:English
Subjects:
Chemical reduction
Coordination polymers
Crystallography
Electrical resistivity
Hydrazines
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Summary:A flexible coordination polymer with a naphthalenediimide core exhibited reversible desorption-adsorption of solvent molecules and an enhancement of electrical conductivity (∼10 −7 S cm −1 ) upon chemical reduction using hydrazine. Postsynthetic chemical reduction enhanced the electrical conductivity of a new flexible 1D coordination network with a naphthalenediimide (NDI)-based ligand.
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc03062g