Effective and simultaneous removal of organic/inorganic arsenic using polymer-based hydrated iron oxide adsorbent: Capacity evaluation and mechanism

• Published in: The Science of the total environment 2020-11, Vol.742, p.140508-140508, Article 140508
• Main Authors: Liu, Biming, Liu, Zhenxue, Wu, Haixia, Pan, Shunlong, Cheng, Xing, Sun, Yongjun, Xu, Yanhua
• Format: Article
• Language: English
• Subjects: Hydrated iron oxide; Inorganic arsenic; Nanocomposite adsorbent; p-Arsanilic acid; Simultaneous removal
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2020.140508

In this study, resin-based hydrated iron oxide (HFOR) composites were prepared and used as a functional adsorbent for the simultaneous removal of p-Arsanilic acid (p-ASA) and arsenate (As (V)). The effects of solution pH and coexisting substances on the adsorption of different arsenic species were also investigated. Results showed that the coexisting substances slightly affected the adsorption process of two arsenic species. Analysis of the adsorption behavior, isotherm equilibrium, and adsorption kinetics, as well as that results of the X-ray photoelectron spectroscopy, zeta potential, and other analytical methods revealed that the satisfactory adsorption performance of HFOR can be attributed to the electrostatic interactions induced by the positively charged groups and the coordination of the hydrated iron oxide nanoparticles, which exhibited excellent specific adsorption for both arsenic species. Moreover, HFOR showed high acid and alkali resistance and reusability, as well as a constant co-removal performance for different arsenic species in five consecutive operating cycles (55 mg As/g of As(V) and 18 mg/g of p-ASA). Results of continuous running fixed-bed column experiments confirmed that HFOR enabled excellent simultaneous adsorption for p-ASA and As(V). [Display omitted] •Resin-based hydrated iron oxide (HFOR) composites were prepared with functional structure.•Simultaneous removal of organic and inorganic arsenic pollutants by HFOR was achieved.•The simultaneous adsorption capacity of As(V) and pAA by HFOR reached 1140 BV.•HFOR exhibited excellent acid and alkali resistance and reusability.