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Normal-pulse-voltage-assisted in situ fabrication of graphene-wrapped MOF-derived CuO nanoflowers for water oxidation

Chemical vapor deposition (CVD) and normal pulse voltage (NPV) are adopted to construct high-quality graphene-wrapped CuO nanoflowers grown in situ on copper foam (CuO NP@G/CF) as an efficient oxygen evolution reaction (OER) electrocatalyst. The CuO NF@G/CF electrode exhibits a small overpotential o...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-08, Vol.56 (62), p.8750-8753
Main Authors: Wang, Ying, Wang, Shiqi, Liu, Dayan, Zhou, Lin, Du, Ran, Li, Ting-Ting, Miao, Tingting, Qian, Jinjie, Hu, Yue, Huang, Shaoming
Format: Article
Language:English
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Summary:Chemical vapor deposition (CVD) and normal pulse voltage (NPV) are adopted to construct high-quality graphene-wrapped CuO nanoflowers grown in situ on copper foam (CuO NP@G/CF) as an efficient oxygen evolution reaction (OER) electrocatalyst. The CuO NF@G/CF electrode exhibits a small overpotential of 320 mV to drive a current density of 10 mA cm −2 with a low Tafel slope of 63.1 mV dec −1 . This enhancement in OER performance stems from the synergistic effect between highly conductive graphene and hierarchically porous CuO nanoflowers with a number of high-density active sites and open spaces.
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc03132a