Gallium Phosphide Nanowires in a Free-Standing, Flexible, and Semitransparent Membrane for Large-Scale Infrared-to-Visible Light Conversion

• Published in: ACS nano 2020-08, Vol.14 (8), p.10624-10632
• Main Authors: Fedorov, Vladimir V, Bolshakov, Alexey, Sergaeva, Olga, Neplokh, Vladimir, Markina, Daria, Bruyere, Stephanie, Saerens, Grégoire, Petrov, Mihail I, Grange, Rachel, Timofeeva, Maria, Makarov, Sergey V, Mukhin, Ivan S
• Format: Article
• Language: English
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/acsnano.0c04872

Engineering of nonlinear optical response in nanostructures is one of the key topics in nanophotonics, as it allows for broad frequency conversion at the nanoscale. Nevertheless, the application of the developed designs is limited by either high cost of their manufacturing or low conversion efficiencies. This paper reports on the efficient second-harmonic generation in a free-standing GaP nanowire array encapsulated in a polymer membrane. Light coupling with optical resonances and field confinement in the nanowires together with high nonlinearity of GaP material yield a strong second-harmonic signal and efficient near-infrared (800–1200 nm) to visible upconversion. The fabricated nanowire-based membranes demonstrate high flexibility and semitransparency for the incident infrared radiation, allowing utilizing them for infrared imaging, which can be easily integrated into different optical schemes without disturbing the visualized beam.