Nickel-Catalyzed Thiocarbonylation of Arylboronic Acids with Sulfonyl Chlorides for the Synthesis of Thioesters

An interesting procedure for thioester synthesis via nickel-catalyzed thiocarbonylation of arylboronic acid with sulfonyl chlorides as the sulfur source has been explored. Using Mo­(CO)6 as a solid CO surrogate and reductant, a broad range of thioesters were obtained in moderate to good yields with...

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Bibliographic Details
Published in:Organic letters 2020-08, Vol.22 (16), p.6671-6676
Main Authors: Qi, Xinxin, Bao, Zhi-Peng, Yao, Xin-Tong, Wu, Xiao-Feng
Format: Article
Language:English
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Summary:An interesting procedure for thioester synthesis via nickel-catalyzed thiocarbonylation of arylboronic acid with sulfonyl chlorides as the sulfur source has been explored. Using Mo­(CO)6 as a solid CO surrogate and reductant, a broad range of thioesters were obtained in moderate to good yields with good functional group tolerance.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.0c02541