Evolution of polaron states into bipolarons in polypyrrole

The kinetics of polaron recombination into bipolarons in polypyrrole has been studied by optical-absorption spectroscopy on films doped in situ in an electrochemical cell. ERS studies confirm that the metastable states possess spin, while the stable states do not. The data reveal a slow evolution, c...

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Published in:Physical review letters 1984-09, Vol.53 (10), p.1005-1008
Main Authors: KAUFMAN, J. H, COLANERI, N, SCOTT, J. C, STREET, G. B
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Structure, morphology and analysis
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description The kinetics of polaron recombination into bipolarons in polypyrrole has been studied by optical-absorption spectroscopy on films doped in situ in an electrochemical cell. ERS studies confirm that the metastable states possess spin, while the stable states do not. The data reveal a slow evolution, consistent with polaron-diffusion rates limited by the mobility of the accompanying counterion.
doi_str_mv 10.1103/PhysRevLett.53.1005
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source American Physical Society:Jisc Collections:APS Read and Publish 2023-2025 (reading list)
subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Structure, morphology and analysis
title Evolution of polaron states into bipolarons in polypyrrole
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